A Porous Cu(II)-MOF with Proline Embellished Cavity: Cooperative Catalysis for the Baylis-Hillman Reaction

被引：32

作者：

De, Dinesh ^{[1
]}

Pal, Tapan K. ^{[1
]}

Bharadwaj, Parimal K. ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India

来源：

INORGANIC CHEMISTRY | 2016年 / 55卷 / 14期

关键词：

METAL-ORGANIC FRAMEWORKS; LEWIS-ACID SITES; CO2; CONVERSION; SIZE; FUNCTIONALIZATION; PERFORMANCE; ADSORPTION; CAPACITY; POROSITY;

D O I：

10.1021/acs.inorgchem.6b01211

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

L-Proline has been covalently attached in a rigid linear ligand, H4L, having an isophthalate moiety at each terminal to form the chiral ligand, H4LPRO. This linker has been used for the construction of a porous MOF, LCuPRO. The free L-proline moiety in the cavity of the framework in the presence of imidazole as a cocatalyst functions synergistically to catalyze the Baylis-Hillman reaction between alpha,beta-unsaturated carbonyl compounds and aromatic aldehydes. High porosity of the framework is proven by the nitrogen adsorption isotherm.

引用

页码：6842 / 6844

页数：3

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