A Porous Cu(II)-MOF with Proline Embellished Cavity: Cooperative Catalysis for the Baylis-Hillman Reaction

被引：32
作者：
De, Dinesh [1 ]
Pal, Tapan K. [1 ]
Bharadwaj, Parimal K. [1 ]
机构：
[1] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India
来源：
INORGANIC CHEMISTRY | 2016年 / 55卷 / 14期
关键词：
METAL-ORGANIC FRAMEWORKS; LEWIS-ACID SITES; CO2; CONVERSION; SIZE; FUNCTIONALIZATION; PERFORMANCE; ADSORPTION; CAPACITY; POROSITY;
D O I：
10.1021/acs.inorgchem.6b01211
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
L-Proline has been covalently attached in a rigid linear ligand, H4L, having an isophthalate moiety at each terminal to form the chiral ligand, H4LPRO. This linker has been used for the construction of a porous MOF, LCuPRO. The free L-proline moiety in the cavity of the framework in the presence of imidazole as a cocatalyst functions synergistically to catalyze the Baylis-Hillman reaction between alpha,beta-unsaturated carbonyl compounds and aromatic aldehydes. High porosity of the framework is proven by the nitrogen adsorption isotherm.
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收藏
页码：6842 / 6844
页数：3
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