Manganese- or iron-catalyzed homocoupling of Grignard reagents using atmospheric oxygen as an oxidant

被引：221
作者：
Cahiez, Gerard [1 ]
Moyeux, Alban [1 ]
Buendia, Julien [1 ]
Duplais, Christophe [1 ]
机构：
[1] UCP, ESCOM, Lab Synth Organ Select & Chim Organomet, CNRS,UMR 8123, F-95092 Cergy Pontoise, France
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 45期
关键词：
D O I：
10.1021/ja075417k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Atmospheric oxygen was used for the first time as an oxidant in metal-catalyzed homocoupling of Grignard reagents. These manganese- or iron-catalyzed reactions are efficient, cheap, and eco-friendly. They are applicable to the large-scale synthesis of symmetrical conjugated compounds.
引用
收藏
页码：13788 / +
页数：3
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