Crystal structure of a chiral nitrido-manganese salen complex. The nitrogen analogue to the intermediate in the Jacobsen epoxidation reaction

被引：23

作者：

Jepsen, AS ^{[1
]}

Roberson, M ^{[1
]}

Hazell, RG ^{[1
]}

Jorgensen, KA ^{[1
]}

机构：

[1] Aarhus Univ, Dept Chem, Ctr Met Catalyzed React, DK-8000 Aarhus C, Denmark

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 15期

关键词：

D O I：

10.1039/a802592d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A chiral nitrido-manganese salen complex has been synthesised and characterised by X-ray diffraction; the geometrical and electronic structure of the complex are discussed in relation to the intermediate in asymmetric reactions.

引用

页码：1599 / 1600

页数：2

共 24 条

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