Borane catalyzed polymerization and depolymerization reactions controlled by Lewis acidic strength

被引：17
作者：
Andrea, Kori A. [1 ]
Wheeler, Mikhailey D. [1 ]
Kerton, Francesca M. [1 ]
机构：
[1] Mem Univ Newfoundland, Dept Chem, 230 Elizabeth Ave, St John, NF A1C 5S7, Canada
来源：
CHEMICAL COMMUNICATIONS | 2021年 / 57卷 / 59期
基金：
加拿大自然科学与工程研究理事会;
关键词：
ONE-POT SYNTHESIS; CARBON-DIOXIDE; ORGANIC CARBONATES; CYCLIC ANHYDRIDES; ABA BLOCK; EPOXIDES; COPOLYMERIZATION; TERPOLYMERIZATION; CO2; POLYCARBONATES;
D O I：
10.1039/d1cc02218k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Triphenylborane catalyzes the polymerization of anhydrides and epoxides along with the block co-polymerization of anhydride/epoxides with epoxides/CO2. Switching to the more Lewis acidic borane, tris(pentafluorophenyl)borane, the carbonate block of the polymer could be selectively depolymerized to yield the corresponding cyclic carbonate opening the door towards chemical repurposing of the polymer.
引用
收藏
页码：7320 / 7322
页数：3
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  • [21] The broadening reach of frustrated Lewis pair chemistry
    Stephan, Douglas W.
    [J]. SCIENCE, 2016, 354 (6317)
  • [22] Frustrated Lewis Pairs: From Concept to Catalysis
    Stephan, Douglas W.
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2015, 48 (02) : 306 - 316
  • [23] Switch Catalysis To Deliver Multi-Block Polyesters from Mixtures of Propene Oxide, Lactide, and Phthalic Anhydride
    Stoesser, Tim
    Mulryan, Daniel
    Williams, Charlotte K.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (51) : 16893 - 16897
  • [24] Selective Polymerization Catalysis from Monomer Mixtures: Using a Commercial Cr-Salen Catalyst To Access ABA Block Polyesters
    Stoesser, Tim
    Williams, Charlotte K.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (21) : 6337 - 6341
  • [25] Switchable Catalysis Improves the Properties of CO2-Derived Polymers: Poly(cyclohexene carbonate-b-ε-decalactone-b-cyclohexene carbonate) Adhesives, Elastomers, and Toughened Plastics
    Sulley, Gregory S.
    Gregory, Georgina L.
    Chen, Thomas T. D.
    Carrodeguas, Leticia Pena
    Trott, Gemma
    Santmarti, Alba
    Lee, Koon-Yang
    Terrill, Nicholas J.
    Williams, Charlotte K.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (09) : 4367 - 4378
  • [26] Renewable polycarbonates and polyesters from 1,4-cyclohexadiene
    Winkler, Matthias
    Romain, Charles
    Meier, Michael A. R.
    Williams, Charlotte K.
    [J]. GREEN CHEMISTRY, 2015, 17 (01) : 300 - 306
  • [27] Scalable Bifunctional Organoboron Catalysts for Copolymerization of CO2 and Epoxides with Unprecedented Efficiency
    Yang, Guan-Wen
    Zhang, Yao-Yao
    Xie, Rui
    Wu, Guang-Peng
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (28) : 12245 - 12255
  • [28] Metal-Free Approach for a One-Pot Construction of Biodegradable Block Copolymers from Epoxides, Phthalic Anhydride, and CO2
    Ye, Shuxian
    Wang, Wenjing
    Liang, Jiaxin
    Wang, Shuanjin
    Xiao, Min
    Meng, Yuezhong
    [J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING, 2020, 8 (48): : 17860 - 17867
  • [29] Metal-Free Alternating Copolymerization of CO2 with Epoxides: Fulfilling "Green" Synthesis and Activity
    Zhang, Dongyue
    Boopathi, Senthil K.
    Hadjichristidis, Nikos
    Gnanou, Yves
    Feng, Xiaoshuang
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (35) : 11117 - 11120
  • [30] Scalable, Durable, and Recyclable Metal-Free Catalysts for Highly Efficient Conversion of CO2to Cyclic Carbonates
    Zhang, Yao-Yao
    Yang, Guan-Wen
    Xie, Rui
    Yang, Li
    Li, Bo
    Wu, Guang-Peng
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (51) : 23291 - 23298
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