Borane catalyzed polymerization and depolymerization reactions controlled by Lewis acidic strength

被引：17
作者：
Andrea, Kori A. [1 ]
Wheeler, Mikhailey D. [1 ]
Kerton, Francesca M. [1 ]
机构：
[1] Mem Univ Newfoundland, Dept Chem, 230 Elizabeth Ave, St John, NF A1C 5S7, Canada
来源：
CHEMICAL COMMUNICATIONS | 2021年 / 57卷 / 59期
基金：
加拿大自然科学与工程研究理事会;
关键词：
ONE-POT SYNTHESIS; CARBON-DIOXIDE; ORGANIC CARBONATES; CYCLIC ANHYDRIDES; ABA BLOCK; EPOXIDES; COPOLYMERIZATION; TERPOLYMERIZATION; CO2; POLYCARBONATES;
D O I：
10.1039/d1cc02218k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Triphenylborane catalyzes the polymerization of anhydrides and epoxides along with the block co-polymerization of anhydride/epoxides with epoxides/CO2. Switching to the more Lewis acidic borane, tris(pentafluorophenyl)borane, the carbonate block of the polymer could be selectively depolymerized to yield the corresponding cyclic carbonate opening the door towards chemical repurposing of the polymer.
引用
收藏
页码：7320 / 7322
页数：3
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  • [1] Functionalized polycarbonates via triphenylborane catalyzed polymerization-hydrosilylation
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    Kerton, Francesca M.
    [J]. RSC ADVANCES, 2019, 9 (46) : 26542 - 26546
  • [2] Triarylborane-Catalyzed Formation of Cyclic Organic Carbonates and Polycarbonates
    Andrea, Kori A.
    Kerton, Francesca M.
    [J]. ACS CATALYSIS, 2019, 9 (03) : 1799 - 1809
  • [3] High elasticity, chemically recyclable, thermoplastics from bio-based monomers: carbon dioxide, limonene oxide and ε-decalactone
    Carrodeguas, Leticia Pena
    Chen, Thomas T. D.
    Gregory, Georgina L.
    Sulley, Gregory S.
    Williams, Charlotte K.
    [J]. GREEN CHEMISTRY, 2020, 22 (23) : 8298 - 8307
  • [4] Study on Thermal Decomposition Behaviors of Terpolymers of Carbon Dioxide, Propylene Oxide, and Cyclohexene Oxide
    Chen, Shaoyun
    Xiao, Min
    Sun, Luyi
    Meng, Yuezhong
    [J]. INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 2018, 19 (12)
  • [5] Pentablock Copolymer from Tetracomponent Monomer Mixture Using a Switchable Dizinc Catalyst
    Chen, Thomas T. D.
    Zhu, Yunqing
    Williams, Charlotte K.
    [J]. MACROMOLECULES, 2018, 51 (14) : 5346 - 5351
  • [6] Depolymerization of Polycarbonates Derived from Carbon Dioxide and Epoxides to Provide Cyclic Carbonates. A Kinetic Study
    Darensbourg, Donald J.
    Wei, Sheng-Hsuan
    [J]. MACROMOLECULES, 2012, 45 (15) : 5916 - 5922
  • [7] Sustainable conversion of carbon dioxide: the advent of organocatalysis
    Fiorani, Giulia
    Guo, Wusheng
    Kleij, Arjan W.
    [J]. GREEN CHEMISTRY, 2015, 17 (03) : 1375 - 1389
  • [8] CO2-Tuned Sequential Synthesis of Stereoblock Copolymers Comprising a Stereoregularity-Adjustable Polyester Block and an Atactic CO2-Based Polycarbonate Block
    Han, Bing
    Liu, Binyuan
    Ding, Huining
    Duan, Zhongyu
    Wang, Xianhong
    Theato, Patrick
    [J]. MACROMOLECULES, 2017, 50 (23) : 9207 - 9215
  • [9] Copolymerization and terpolymerization of carbon dioxide/propylene oxide/phthalic anhydride using a (salen)Co(III) complex tethering four quaternary ammonium salts
    Jeon, Jong Yeob
    Eo, Seong Chan
    Varghese, Jobi Kodiyan
    Lee, Bun Yeoul
    [J]. BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2014, 10 : 1787 - 1795
  • [10] Pre-rate-determining selectivity in the terpolymerization of epoxides, cyclic anhydrides, and CO2:: A one-step route to diblock copolymers
    Jeske, Ryan C.
    Rowley, John M.
    Coates, Geoffrey W.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (32) : 6041 - 6044
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