Preparation and Properties of Emulsion Coating of Polyacrylate Modified by In-situ Nano-hybrid Silica

被引:0
|
作者
Gao, Jungang [1 ]
Lv, Hongqiu [1 ]
Zhang, Xuefang [1 ]
机构
[1] Hebei Univ, Coll Chem & Environm Sci, Baoding 071002, Peoples R China
来源
ADVANCED MATERIALS, PTS 1-4 | 2011年 / 239-242卷
关键词
emulsion coating; polyacrylate; nano-silica; nanocomposites;
D O I
10.4028/www.scientific.net/AMR.239-242.3221
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The polyacrylate emulsion coating modified by nano-silica was prepared by In-situ method. Tetraethoxysilane (TEOS) was added as the precursor of SiO2 in the late of the emulsion polymerization. The structure and properties of emulsion and latex film were characterized. The results showed that the nano-hybrid silica/polyacrylate emulsion coating with good performance can be prepared by In-situ method. FTIR analysis indicated that the -Si-O-Si- structure has embodied in the coating film. The particle diameter of emulsion is 378nm when nano-SiO2 content is 6% and the dispersing index is 0.164. The mechanical loss peak temperature (T-p) of coating film with 6% nano-SiO2 is 60.6 degrees C which increase 6 degrees C than pure emulsion film. The nano-hybrid emulsion coating has a good performance, such as good acid-alkali resistance and hardness.
引用
收藏
页码:3221 / 3224
页数:4
相关论文
共 50 条
  • [21] Anchoring of polyacrylate onto silica and formation of polyacrylate/silica nanocomposite particles via in situ emulsion polymerization
    Qi, Dong-ming
    Bao, Yong-zhong
    Huang, Zhi-ming
    Weng, Zhi-xue
    COLLOID AND POLYMER SCIENCE, 2008, 286 (02) : 233 - 241
  • [22] Novel nano magnesium oxide modified hybrid emulsion for antimicrobial coating
    Jana, Tirthankar
    Dhar, Tapan Kumar
    PIGMENT & RESIN TECHNOLOGY, 2025, 54 (03) : 454 - 460
  • [23] APTES/Calcium silica hydrate nano-hybrid composites with enhanced mechanical properties
    Orozco, Carlos A.
    Duque-Redondo, Eduardo
    Aretxabaleta, Xabier M.
    Manzano, Hegoi
    Monteiro, Paulo J. M.
    CONSTRUCTION AND BUILDING MATERIALS, 2024, 438
  • [24] Polyacrylate/silica nanoparticles hybrid emulsion coating with high silica content for high hardness and dry-wear-resistant
    Zhou, Chenglong
    Xu, Shouping
    Pi, Pihui
    Cheng, Jiang
    Wang, Li
    Yang, Jinxin
    Wen, Xiufang
    PROGRESS IN ORGANIC COATINGS, 2018, 121 : 30 - 37
  • [25] A Nano-hybrid Silver Colloidal Suspension Preparation
    Zhao, Jian
    Xie, Xuan
    Zhou, Xiaodong
    IRANIAN POLYMER JOURNAL, 2011, 20 (10) : 845 - 852
  • [26] Preparation of nano-SiO2 modified graphene oxide and its application in polyacrylate emulsion
    Liu, Haiteng
    Pang, Xiaoyan
    Ding, Wei
    Guo, Song
    Ding, Zhiwen
    MATERIALS TODAY COMMUNICATIONS, 2021, 27
  • [27] Graft of nano-silica and its dispersion stability in the in-situ emulsion polymerization
    Li, Yu-Ping
    Wang, Ya-Qiang
    He, Wei-Wei
    Zhang, Run-Yang
    Huang, Li
    Chen, Zhi-Qiao
    Hunan Daxue Xuebao/Journal of Hunan University Natural Sciences, 2006, 33 (03): : 80 - 83
  • [28] Deterioration Process of the Hybrid Films during Wear Test——Polyacrylate Emulsion Modified by Silica Particles
    YANG Mingjun
    DENG Binbin
    YUAN Feifei
    WuhanUniversityJournalofNaturalSciences, 2017, 22 (03) : 191 - 196
  • [29] Effect of Cationic Polyacrylate Emulsion Properties on Paper Coating Properties
    Li Jinli
    Liu Quanxiao
    Xu Wencai
    Lv Yubin
    GREEN PRINTING AND PACKAGING MATERIALS, 2012, 380 : 156 - 159
  • [30] Preparation and Properties of Polysiloxane Coating Modified by Colloidal Silica
    Dong Ze
    Wu Chunchun
    Cheng Di
    Sheng Jiansong
    Cao Xudan
    Yang Hui
    RARE METAL MATERIALS AND ENGINEERING, 2012, 41 : 79 - 82