Bis(acetato-κ2iO,O′)(2,2′:6′,2"-terpyridine-κ3N,N′,N")manganese(II) dihydrate

被引：1
|
作者：
Ha, Kwang [1 ]
机构：
[1] Chonnam Natl Univ, Sch Appl Chem Engn, Res Inst Catalysis, Kwangju 500757, South Korea
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2012年 / 68卷
基金：
新加坡国家研究基金会;
关键词：
LIGANDS;
D O I：
10.1107/S1600536811055802
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The Mn-II ion in the title compound, [Mn(CH3CO2)(2)(C15H11N3)]center dot 2H(2)O, is seven-coordinated in a considerably distorted pentagonal-bipyramidal geometry by three N atoms of the tridentate 2,2':6',2 ''-terpyridine ligand and four O atoms from two acetate anions which chelate the Mn atom via two O atoms. The lateral pyridine rings are slightly inclined to the central pyridine ring, making dihedral angles of 13.6 (2) and 5.7 (2)degrees. The complex and solvent water molecules are linked by intermolecular O-H center dot center dot center dot O hydrogen bonds into a three-dimensional network.
引用
收藏
页码：M124 / U445
页数：12
相关论文
共 50 条
  • [21] Triaquabis(nitrato-O,O′)(2,2′:6′,2"-terpyridine-κ3N)gadalinium(III) nitrate
    Leverd, PC
    Charbonnel, MC
    Dognon, JP
    Lance, M
    Nierlich, M
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1999, 55 : 368 - 370
  • [22] Dichloro(4′-phenyl-2,2′:6′,2"-terpyridine-κ3N)-zinc(II) monohydrate
    Tu, QD
    Li, D
    Wu, T
    Yin, YG
    Ng, SW
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 : M1403 - M1404
  • [23] Crystal structure of bis(2,2 ': 6 ',2 ''-terpyridine- kappa N-3, N ', N '')nickel(II) dicyanidoaurate(I)
    White, Frankie
    Sykora, Richard E.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : 519 - +
  • [24] (Nitro-κN)[2-(phenyldiazenyl-κN2)-pyridine-κN](2,2′:6′,2"-terpyridine-κ3N)ruthenium(II) tetrafluoroborate
    Hansongnern, K
    Saeteaw, U
    Cheng, J
    Liao, FL
    Lu, TH
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2001, 57 : 895 - 896
  • [25] Redetermination of chlorido(2,2′:6′,2"-terpyridine-κ3N,N′,N")gold(I) dichloride trihydrate at 173 K
    Friedrich, Holger B.
    Maguire, Glenn E. M.
    Martincigh, Bice S.
    McKay, Michael G.
    Pietersen, Lauren K.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M1240 - U239
  • [26] (4′-Ferrocenyl-2,2′:6′,2"-terpyridine-κ3N,N′,N")(1,10-phenanthroline-κ2N,N′)copper(II) bis(perchlorate) acetonitrile solvate
    Tang, Si-Ping
    Kuang, Dai-Zhi
    Feng, Yong-Lan
    Chen, Man-Sheng
    Li, Wei
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M731 - U444
  • [27] [2,6-bis(5-chloropyrimidin-2-yl-κN)-pyridine-κN](2,2′:6′,2"-terpyridine-κ3N,N′,N")ruthenium(II) bis(hexa-fluoridophosphate) acetonitrile disolvate
    Medlycott, Elaine A.
    Wang, Jianhua
    Hanan, Garry S.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : M326 - U519
  • [28] catena-Poly[[[(4′-phenyl-2,2′:6′,2"-terpyridine-κ3N,N′,N")zinc(II)]-μ-terephthalato-κ2O:O′] monohydrate]
    Tu, QD
    Yin, YG
    He, J
    Xiang, J
    Lia, D
    Ng, SW
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M254 - M256
  • [29] (2,2′-Bipyridine-κ2N,N′)chlorido[4′-(2,5-dimethoxyphenyl)-2,2′:6′,2"-terpyridine-κ3N,N′,N"]ruthenium(II) hexafluoridophosphate acetonitrile monosolvate
    Oyama, Dai
    Kido, Masato
    Orita, Ai
    Takase, Tsugiko
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1117 - U942
  • [30] Bis[2-(2-pyridylmethyleneamino)benzenesulfonato-κ3N,N′,O]-manganese(II) dihydrate
    Zhao, Cheng-Qiang
    Ou-Yang, Miao
    Huang, Xue-Ren
    Jiang, Yi-Min
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1055 - U430
12345