Multiplicative Extended Kalman Filter (MEKF) is one of the most widely used satellite attitude estimation methods. However, the linearization error's influence is an inherent limitation of this method. In this paper, we aim to analyze this linearization error in the typical satellite attitude determination system with star sensors and gyros. The formulation of linearization error is first derived and the curvature metric is then employed to measure the linearization error. Additionally, we show the reason why linearization error has influence on the performance of MEKF. Based on these analyses, we point out that star sensors' sampling frequency, initial estimated error and accuracy of gyro's measurement model are the factors that could enlarge the system model's linearization error. They all affect the linearization error and attitude determination accuracy by decreasing the predicted accuracy. More concretely, the influence of star sensor's sampling frequency is large, while initial estimated error and gyro's measurement error within a certain range have little influence on MEKF. Finally, combined with plenty of experiments, validity of the above analyses is verified. (C) 2011 Elsevier Masson SAS. All rights reserved.