Performance comparison of dye-sensitized solar cells with different ZnO photoanodes

被引:15
作者
Wu, Ming Ke [1 ]
Ling, Tao [1 ]
Xie, Yang [1 ]
Huang, Xue Guang [2 ]
Du, Xi Wen [1 ]
机构
[1] Tianjin Univ, Sch Mat Sci & Engn, Tianjin Kay Lab Composite & Funct Mat, Tianjin 300072, Peoples R China
[2] State Intellectual Property Off Peoples Republ Ch, Patent Examinat Cooperat Ctr, Beijing 100190, Peoples R China
基金
高等学校博士学科点专项科研基金;
关键词
ELECTROCHEMICAL SYNTHESIS; THIN-FILMS; RECOMBINATION; GROWTH; NANOSTRUCTURES; NANOSHEETS; IMPEDANCE; FABRICATION; EFFICIENCY; TRANSPORT;
D O I
10.1088/0268-1242/26/10/105001
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Different ZnO nanostructures, including separated nanowires, bundled nanowires, nanotubes and dual-layer structure of nanotubes with covered nanoflowers, were synthesized in aqueous solution using a seeded growth process, and these ZnO nanostructures were then used as photoanodes to construct dye-sensitized solar cells (DSSCs). The overall conversion efficiency, dye-adsorption capability, and electron transport of DSSCs were investigated. It was found that surface area and dye adsorption capability of ZnO photoanode were decisive for the performance of DSSCs. Dual-layer structure can achieve an excellent balance between dye adsorption and carrier transport, resulting in higher conversion efficiency over other nanostructures. Our results indicate that ZnO is an excellent material for electron transport, and appropriate ZnO nanostructure is conducive to improving the conversion efficiency of DSSCs.
引用
收藏
页数:6
相关论文
共 31 条
[1]  
Bisquert J, 2002, J PHYS CHEM B, V106, P325, DOI 10.1021/jp01194lg
[2]   Highly efficient and thermally stable organic sensitizers for solvent-free dye-sensitized solar cells [J].
Choi, Hyunbong ;
Baik, Chul ;
Kang, Sang Ook ;
Ko, Jaejung ;
Kang, Moon-Sung ;
Nazeeruddin, Md. K. ;
Graetzel, Michael .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (02) :327-330
[3]  
Elena G, 2011, ENERG ENVIRON SCI, DOI [10.1039/c0ee00500b, DOI 10.1039/C0EE00500B]
[4]   Influence of electrolyte in transport and recombination in dye-sensitized solar cells studied by impedance spectroscopy [J].
Fabregat-Santiago, F ;
Bisquert, J ;
Garcia-Belmonte, G ;
Boschloo, G ;
Hagfeldt, A .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2005, 87 (1-4) :117-131
[5]   Correlation between photovoltaic performance and impedance spectroscopy of dye-sensitized solar cells based on ionic liquids [J].
Fabregat-Santiago, Francisco ;
Bisquert, Juan ;
Palomares, Emilio ;
Otero, Luis ;
Kuang, Daibin ;
Zakeeruddin, Shaik M. ;
Gratzel, Michael .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (17) :6550-6560
[6]   Characterization of nanostructured hybrid and organic solar cells by impedance spectroscopy [J].
Fabregat-Santiago, Francisco ;
Garcia-Belmonte, Germa ;
Mora-Sero, Ivan ;
Bisquert, Juan .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (20) :9083-9118
[7]   ZnO nanosheets with ordered pore periodicity via colloidal crystal template assisted electrochemical deposition [J].
Fu, M ;
Zhou, J ;
Xiao, QF ;
Li, B ;
Zong, RL ;
Chen, W ;
Zhang, J .
ADVANCED MATERIALS, 2006, 18 (08) :1001-+
[8]   Photoelectrochemical cells [J].
Grätzel, M .
NATURE, 2001, 414 (6861) :338-344
[9]   Electrochemical Impedance Spectroscopy Characterization of Electron Transport and Recombination in ZnO Nanorod Dye-Sensitized Solar Cells [J].
He, Chuan ;
Zheng, Zhi ;
Tang, Huili ;
Zhao, Linan ;
Lu, Fang .
JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (24) :10322-10325
[10]   Simple solvothermal route to synthesize ZnO nanosheets, nanonails, and well-aligned nanorod arrays [J].
Kar, Soumitra ;
Dev, Apurba ;
Chaudhuri, Subhadra .
JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (36) :17848-17853