Manifestation of quasi-symmetry of the cation sites of Gd2SiO5, Y2SiO5, and Lu2SiO5 in the spectra of the impurity ion Pr3+

被引:9
|
作者
Malyukin, YV
Borisov, RS
Zhmurin, PN
Lebedenko, AN
Grinev, BV
Znamensky, NV
Manykin, ÉA
Orlov, YV
Petrenko, EA
Yukina, TG
机构
[1] Natl Acad Sci Ukraine, Inst Single Crystals, UA-61001 Kharkov, Ukraine
[2] Kurchatov Inst Russian Res Ctr, Moscow 123182, Russia
关键词
D O I
10.1063/1.1388423
中图分类号
O59 [应用物理学];
学科分类号
摘要
The quasi-symmetry of the inequivalent cation sites in the crystals Gd2SiO5, Y2SiO5, and Lu2SiO5 is established on the basis of an analysis of the features of the low-temperature optical spectra of the impurity ion Pr3+. One type of cation site of the crystals Y2SiO5 and Lu2SiO5 manifests the quasi-symmetry of a distorted octahedron, and the other type, that of a distorted tetrahedron. The parameters characterizing the energy spectrum of the free Pr3+ ion in the crystalline field of the cation sites are determined. (C) 2001 American Institute of Physics.
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页码:574 / 578
页数:5
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