2D Hexagonal Tilings Based on Triangular and Hexagonal Structural Units in the Self-Assembly of Thiacalix[4]arene Tetrasulfonate on an Au(111) Surface

被引：6
|
作者：
Chen, Ting [1 ,2 ]
Yan, Hui-Juan [1 ,2 ]
Zhang, Xu [1 ,2 ,3 ]
Wang, Dong [1 ,2 ]
Wan, Li-Jun [1 ,2 ]
机构：
[1] Chinese Acad Sci, Inst Chem, Beijing 100190, Peoples R China
[2] Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
[3] Chinese Acad Sci, Grad Sch, Beijing 100190, Peoples R China
来源：
CHEMISTRY-AN ASIAN JOURNAL | 2011年 / 6卷 / 07期
基金：
中国国家自然科学基金;
关键词：
calixarenes; nanostructures; polymorphism; scanning tunneling microscopy; self-assembly; SCANNING-TUNNELING-MICROSCOPY; ACID; ORGANIZATION; INTERFACE; COMPLEXES; SYMMETRY; CRYSTALS; NETWORK; METAL; STM;
D O I：
10.1002/asia.201000640
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The formation of several molecular 2D tilings with long-range periodicity, including the Kagome network, distorted Kagome network, and snub trihexagonal tiling from the adsorption and assembly of thiacalix[4]arene tetrasulfonate (TCAS) at the 0.1 M HClO(4)/Au(111) interface has been investigated by electrochemical scanning tunneling microscopy (STM). The internal structures of the tilings have been disclosed by high-resolution STM images. The basic structural motifs, namely, the tiles of these tilings are similar, including triangular units and hexagonal units. Due to the different arrangement of the molecules within the triangular units, tiles with different configurations are formed, which further result in the polymorphism of the 2D tiling. This result is of significance for understanding the formation of 2D tiling as well as the design and construction of molecular self-assembled nanostructures.
引用
收藏
页码：1811 / 1816
页数：6
相关论文
共 11 条
  • [1] Self-Assembly and Magnetic Order of Bi-Molecular 2D Spin Lattices of M(II,III) Phthalocyanines on Au(111)
    Baljozovic, Milos
    Liu, Xunshan
    Popova, Olha
    Girovsky, Jan
    Nowakowski, Jan
    Rossmann, Harald
    Nijs, Thomas
    Moradi, Mina
    Mousavi, S. Fatemeh
    Plumb, Nicholas C.
    Radovic, Milan
    Ballav, Nirmalya
    Dreiser, Jan
    Decurtins, Silvio
    Pasti, Igor A.
    Skorodumova, Natalia, V
    Liu, Shi-Xia
    Jung, Thomas A.
    MAGNETOCHEMISTRY, 2021, 7 (08)
  • [2] On-Surface Metalation and 2D Self-Assembly of Pyrphyrin Molecules Into Metal-Coordinated Networks on Cu(111)
    Li, Jingyi
    Wackerlin, Christian
    Schnidrig, Stephan
    Joliat, Evelyne
    Alberto, Roger
    Ernst, Karl-Heinz
    HELVETICA CHIMICA ACTA, 2017, 100 (01)
  • [3] Erecting buckybowls onto their edge: 2D self-assembly of terphenylcorannulene on the Cu(111) surface
    Stockl, Quirin S.
    Wu, Tsun-Cheng
    Mairena, Anais
    Wu, Yao-Ting
    Ernst, Karl-Heinz
    FARADAY DISCUSSIONS, 2017, 204 : 429 - 437
  • [4] Self-assembly and morphology change of four organic-polyoxometalate hybrids with different solid structures from 2D lamellar to 3D hexagonal forms
    Tan, Chunxia
    JOURNAL OF MOLECULAR STRUCTURE, 2017, 1130 : 276 - 283
  • [5] A photoelectrochemical aptasensor for tetracycline based on the self-assembly of 2D MoS2 on a 3D ZnO/Au/ITO electrode
    Li, Weixin
    Wang, Xinyang
    Chen, Lifen
    Luo, Fang
    Guo, Longhua
    Lin, Cuiying
    Wang, Jian
    Qiu, Bin
    Lin, Zhenyu
    ANALYST, 2023, 148 (20) : 4995 - 5001
  • [6] Designing nanoporous crystalline materials by self-assembly:: 2D hydrogen-bonded networks from upper rim calix[4]arene diamide derivatives
    Baldini, Laura
    Sansone, Francesco
    Massera, Chiara
    Casnati, Alessandro
    Ugozzoli, Franco
    Ungaro, Rocco
    INORGANICA CHIMICA ACTA, 2007, 360 (03) : 970 - 980
  • [7] Selective and efficacious photoelectrochemical detection of ciprofloxacin based on the self-assembly of 2D/2D g-C3N4/Ti3C2 composites
    Yuan, Chen
    He, Zhilong
    Chen, Qiaowei
    Wang, Xuandong
    Zhai, Chunyang
    Zhu, Mingshan
    APPLIED SURFACE SCIENCE, 2021, 539
  • [8] Self-Assembly of 1D, 2D, and 3D Lanthanide-Metal Coordination Polymers Based on a 2-(Pyridin-4-yl)-4,5-imidazoledicarboxylate Linker: Synthesis, Structures, and Luminescence
    Sun, Lin
    Li, Gui-Zhu
    Xu, Mei-Hua
    Li, Xiao-Jian
    Li, Jian-Rong
    Deng, Hong
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2012, (11) : 1764 - 1772
  • [9] From a lamellar to hexagonal self-assembly of bis(4,4′-(m,m′-di(dodecyloxy)phenyl)-2,2′-difluoro-1,3,2-dioxaborin) molecules:: A trans-to-cis-isomerization-induced structural transition studied with STM
    Rohde, Dirk
    Yan, Cun-Ji
    Yan, Hui-Juan
    Wan, Li-Jun
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (24) : 3996 - 4000
  • [10] Self-assembly of azine-based hydrolysis of pyridine and isatin oxamohydrazides with AgNO3; synthesis and structural studies of a novel four coordinated Ag(I)-azine 2D coordination polymer
    Soliman, Saied M.
    Barakat, Assem
    INORGANICA CHIMICA ACTA, 2019, 490 : 227 - 234
12