Highly selective NH3 gas sensor based on polypyrrole/Ti3C2Tx nanocomposites operating at room temperature

被引:31
作者
Chen, Pu [1 ]
Zhao, Zhihua [2 ]
Shao, Zhigang [1 ,3 ]
Tian, Ye [2 ]
Li, Bo [2 ]
Huang, Bo [1 ]
Zhang, Shuaiwen [2 ]
Liu, Chunbo
Shen, Xiaoqing [1 ]
机构
[1] Zhengzhou Univ, Coll Mat Sci & Engn, Zhengzhou 450052, Peoples R China
[2] Henan Univ Technol, Coll Mech & Elect Engn, Zhengzhou 450052, Peoples R China
[3] Univ Toulouse, Lab Coordinat Chem, CNRS UPR 8241, 205 Route Narbonne, F-31077 Toulouse, France
关键词
AMMONIA SENSOR; THIN-FILM; PERFORMANCE; STEP;
D O I
10.1007/s10854-022-07792-y
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Semiconducting nanomaterials with different sizes and shapes have wide applications in the field of electronics, and one of the key pathway to improve their performance is by recombination of different materials. In our innovative work, the nanocomposites of polypyrrole (PPy) and MXene were prepared by a simple in situ polymerization reaction. The samples were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). The samples were made into sensors, and the gas sensitivities of the materials were investigated under different test conditions. The results showed that the response value of PPy/MXene-12 sensor to 100 ppm ammonia at room temperature was 2.38 times than that of pure PPy and 6.38 times than that of pure MXene. In addition, the sensor has excellent selectivity and low detection limit, which demonstrate the excellent practicability of them in the field of Internet of Things (IoT).
引用
收藏
页码:6168 / 6177
页数:10
相关论文
共 45 条
[1]   Guidelines for Synthesis and Processing of Two-Dimensional Titanium Carbide (Ti3C2TX MXene) [J].
Alhabeb, Mohamed ;
Maleski, Kathleen ;
Anasori, Babak ;
Lelyukh, Pavel ;
Clark, Leah ;
Sin, Saleesha ;
Gogotsi, Yury .
CHEMISTRY OF MATERIALS, 2017, 29 (18) :7633-7644
[2]   Polyaniline@SnO2 heterojunction loading on flexible PET thin film for detection of NH3 at room temperature [J].
Bai, Shouli ;
Tian, Yanli ;
Cui, Meng ;
Sun, Jianhua ;
Tian, Ye ;
Luo, Ruixian ;
Chen, Aifan ;
Li, Dianqing .
SENSORS AND ACTUATORS B-CHEMICAL, 2016, 226 :540-547
[3]   Simple and low-temperature polyaniline-based flexible ammonia sensor: a step towards laboratory synthesis to economical device design [J].
Bandgar, D. K. ;
Navale, S. T. ;
Nalage, S. R. ;
Mane, R. S. ;
Stadler, F. J. ;
Aswal, D. K. ;
Gupta, S. K. ;
Patil, V. B. .
JOURNAL OF MATERIALS CHEMISTRY C, 2015, 3 (36) :9461-9468
[4]   Electrospun α-Fe2O3 nanostructures for supercapacitor applications [J].
Binitha, G. ;
Soumya, M. S. ;
Madhavan, Asha Anish ;
Praveen, P. ;
Balakrishnan, A. ;
Subramanian, K. R. V. ;
Reddy, M. V. ;
Nair, Shantikumar V. ;
Nair, A. Sreekumaran ;
Sivakumar, N. .
JOURNAL OF MATERIALS CHEMISTRY A, 2013, 1 (38) :11698-11704
[5]   Pseudocapacitive Electrodes Produced by Oxidant-Free Polymerization of Pyrrole between the Layers of 2D Titanium Carbide (MXene) [J].
Boota, Muhammad ;
Anasori, Babak ;
Voigt, Cooper ;
Zhao, Meng-Qiang ;
Barsoum, Michel W. ;
Gogotsi, Yury .
ADVANCED MATERIALS, 2016, 28 (07) :1517-1522
[6]   α-Fe2O3 loaded less-defective graphene sheets as chemiresistive gas sensor for selective sensing of NH3 [J].
Haridas, Vijayasree ;
Sukhananazerin, A. ;
Sneha, J. Mary ;
Pullithadathil, Biji ;
Narayanan, Binitha .
APPLIED SURFACE SCIENCE, 2020, 517 (517)
[7]   CuO Nanoparticles/Ti3C2Tx MXene Hybrid Nanocomposites for Detection of Toluene Gas [J].
Hermawan, Angga ;
Zhang, Biao ;
Taufik, Ardiansyah ;
Asakura, Yusuke ;
Hasegawa, Takuya ;
Zhu, Jianfeng ;
Shi, Pei ;
Yin, Shu .
ACS APPLIED NANO MATERIALS, 2020, 3 (05) :4755-4766
[8]   Breath Ammonia Analysis: Clinical Application and Measurement [J].
Hibbard, Troy ;
Killard, Anthony J. .
CRITICAL REVIEWS IN ANALYTICAL CHEMISTRY, 2011, 41 (01) :21-35
[9]   Three-dimensional carambola-like MXene/polypyrrole composite produced by one-step co-electrodeposition method for electrochemical energy storage [J].
Jian, Xuan ;
He, Min ;
Chen, Lu ;
Zhang, Mi-mi ;
Li, Rui ;
Gao, Lou-jun ;
Fu, Feng ;
Liang, Zhen-hai .
ELECTROCHIMICA ACTA, 2019, 318 :820-827
[10]   Inquest of highly sensitive, selective and stable ammonia (NH3) gas sensor: Structural, morphological and gas sensing properties of polyvinylpyrrolidone (PVP)/CuO nanocomposite [J].
Khan, Hizb Ullah ;
Tariq, Muhammad ;
Shah, Mutabar ;
Iqbal, Mahmood ;
Jan, Muhammad Tariq .
SYNTHETIC METALS, 2020, 268 (268)