Intervalence Charge-Transfer System by 1D Assembly of New Mixed-Valence Octanuclear CuI/CuII/CuIII Cluster Units

被引：16

作者：

Okubo, Takashi ^{[1
,2
]}

Kuwamoto, Hiroyasu ^{[1
]}

Kim, Kyung Ho ^{[1
]}

Hayami, Shinya ^{[3
]}

Yamano, Akihito ^{[4
]}

Shiro, Motoo ^{[4
]}

Maekawa, Masahiko ^{[1
]}

Kuroda-Sowa, Takayoshi ^{[1
]}

机构：

[1] Kinki Univ, Sch Sci & Engn, Higashiosaka, Osaka 5778502, Japan

[2] Japan Sci & Technol Agcy, PRESTO, Kawaguchi, Saitama 3320012, Japan

[3] Kumamoto Univ, Fac Sci, Dept Chem, Kumamoto 8608555, Japan

[4] Rigaku Corp, Akishima, Tokyo 1968666, Japan

来源：

INORGANIC CHEMISTRY | 2011年 / 50卷 / 07期

关键词：

COORDINATION POLYMERS; CRYSTAL-STRUCTURES; MMX-CHAIN; COMPLEXES; RUTHENIUM; BEHAVIOR; SERIES;

D O I：

10.1021/ic101794u

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of Cu(Hm-dtc)(2), Br-2, and CuBr2 yielded a new mixed-valence octanuclear Cu-I/Cu-II/Cu-III cluster, encapsulating a Br anion in the center of the cluster cage. The octanuclear cluster units form a 1D assemblage, which induces intervalence charge-transfer transitions from Cu-II ions to Cu-III ions between the clusters.

引用

页码：2708 / 2710

页数：3

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