Catalytic hydrothermal gasification of cellulose and glucose

被引：95

作者：

Fang, Zhen ^{[1
]}

Minowa, Tomoaki ^{[2
]}

Fang, Chun ^{[3
]}

Smith, Richard L., Jr. ^{[4
]}

Inomata, Hiroshi ^{[4
]}

Kozinski, Janusz A. ^{[5
]}

机构：

[1] Chinese Acad Sci, Xishuangbanna Trop Botan Garden, Biomass Grp, Kunming 650223, Peoples R China

[2] Natl Inst Adv Ind Sci & Technol, Biomass Technol Res Ctr, Hiroshima 7370197, Japan

[3] Washington State Univ, AgWeatherNet Program, Prosser, WA 99350 USA

[4] Tohoku Univ, Res Ctr Supercrit Fluid Technol, Dept Chem Engn, Sendai, Miyagi 9808579, Japan

[5] Univ Saskatchewan, Dept Chem Engn, Saskatoon, SK S7N 5A9, Canada

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2008年 / 33卷 / 03期

关键词：

hydrothermal; hydrogen; cellulose; glucose; sub-and supercritical water; gasification; catalyst;

D O I：

10.1016/j.ijhydene.2007.11.023

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An optical micro-reactor (50nL), an autoclave (120mL), and a flow reactor (11.3ml.) were used to study the catalytic hydrothermal gasification of cellulose and glucose. In the micro-reactor experiments, Ni catalyst had a low gasification rate, but 96 wt% rate (35 mo1% H-2) was achieved in the autoclave when Ni/silica-alumina and cellulose were mixed well during slow heating to 350 degrees C (30 min). It was found from the micro-reactor that cellulose completely dissolved in water at 318 degrees C upon fast heating, and that Pt was the most active catalyst for glucose reactions. Gasification of glucose with Pt/gamma-alumina catalyst was examined in flow experiments, where it was found that 67 wt% gasification rate (with up to 44 mol% H-2) could be obtained at 360 degrees C and 30 MPa. (C) 2007 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.

引用

页码：981 / 990

页数：10

共 50 条

[21] Renewable production of methane from woody biomass by catalytic hydrothermal gasification
Waldner, MH
Vogel, F
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2005, 44 (13) : 4543 - 4551
[22] Hydrogen production from olive-pomace by catalytic hydrothermal gasification
Sert, Murat
Gokkaya, Dilek Selvi
Cengiz, Nihal
Ballice, Levent
Yuksel, Mithat
Saglam, Mehmet
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2018, 83 : 90 - 98
[23] Catalytic supercritical gasification of biocrude from hydrothermal liquefaction of cattle manure
Tushar, Mohammad S. H. K.
Dutta, Animesh
Xu, Chunbao
APPLIED CATALYSIS B-ENVIRONMENTAL, 2016, 189 : 119 - 132
[24] A dispersed rutile-TiO2-supported Ni nanoparticle for enhanced gas production from catalytic hydrothermal gasification of glucose
Li, Sha
Zhu, Chao
Guo, Simao
Guo, Liejin
RSC ADVANCES, 2015, 5 (100) : 81905 - 81914
[25] Hydrothermal gasification of glucose using Raney nickel and homogeneous organometallic catalysts
Azadi, P.
Khodadadi, A. A.
Mortazavi, Y.
Farnood, R.
FUEL PROCESSING TECHNOLOGY, 2009, 90 (01) : 145 - 151
[26] Hydrothermal gasification of biomass model compounds (cellulose and lignin alkali) and model mixtures
Madenoglu, Tulay Gungoren
Saglam, Mehmet
Yuksel, Mithat
Ballice, Levent
JOURNAL OF SUPERCRITICAL FLUIDS, 2016, 115 : 79 - 85
[27] Catalytic gasification of glucose to H2 in supercritical water
Ding, Ning
Azargohar, Ramin
Dalai, Ajay K.
Kozinski, Janusz A.
FUEL PROCESSING TECHNOLOGY, 2014, 127 : 33 - 40
[28] EFFICIENT CATALYTIC GASIFICATION OF CELLULOSE FOR PRODUCTION OF HYDROGEN AND CARBON-MONOXIDE
YOKOYAMA, SY
OGI, T
KOGUCHI, K
NAKAMURA, E
CHEMISTRY LETTERS, 1983, (02) : 151 - 154
[29] Catalytic gasification of cellulose and pinewood to H2 in supercritical water
Ding, Ning
Azargohar, Ramin
Dalai, Ajay K.
Kozinski, Janusz A.
FUEL, 2014, 118 : 416 - 425
[30] CATALYTIC HYDROTHERMAL CONVERSION OF GLUCOSE TO LIGHT PETROLEUM ALKANES
Yin, Sudong
Pan, Yanglin
Tan, Zhongchao
ES2010: PROCEEDINGS OF ASME 4TH INTERNATIONAL CONFERENCE ON ENERGY SUSTAINABILITY, VOL 2, 2010, : 1099 - 1103

← 1 2 3 4 5 →