Electrocatalytic properties of thin mesoporous platinum films synthesized utilizing potential-controlled surfactant assembly

被引:125
作者
Choi, KS [1 ]
McFarland, EW
Stucky, GD
机构
[1] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA
[2] Univ Calif Santa Barbara, Dept Chem Engn, Santa Barbara, CA 93106 USA
关键词
D O I
10.1002/adma.200304557
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new method to prepare thin mesoporous platinum films by coupling potential-controlled self-assembly of surfactant-inorganic aggregates and electrodeposition processes was developed. This method uses extremely dilute surfactant solutions to generate films with accessible pores and thermally stable frameworks. Thus, the resulting films possess high surface areas that lead to enhanced electrocatalytic properties towards methanol oxidation compared to those of non-mesoporous platinum films.
引用
收藏
页码:2018 / 2021
页数:4
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