Bis(acetonitrile-κN)diaquabis(perchlorato-κO)copper(II)

被引：0
作者：
Tafeenko, Viktor A. [1 ]
Gurskiy, Stanislav I. [1 ]
Aslanov, Leonid A. [1 ]
机构：
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
LUMINESCENCE PROPERTIES; ACETONITRILE; COPPER(II); 3-CYANO-4-DICYANOMETHYLENE-5-OXO-4,5-DIHYDRO-1H-PYRROL-2-OLATE; ION;
D O I：
10.1107/S1600536811027309
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Cu(ClO4)(2)(CH3CN)(2)(H2O)(2)], the Cu2+ ion, located on a special position (site symmetry 1), is coordinated by six monodentate ligands, viz. an N-coordinated acetonitrile, a perchlorate anion and a water molecule, and their symmetry-related counterparts. The perchlorate anion is disordered over two sets of sites with occupancies of 0.53 (2) and 0.47 (2). The crystal structure is stabilized by O-H center dot center dot center dot O hydrogen bonds involving the perchlorate ion and aqua H atoms.
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页码：M1125 / U1115
页数：10
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