Absorption intensity of stretching overtone states of silane and germane

被引：16
作者：
Lin, H
Wang, D
Chen, XY
Wang, XG
Zhou, ZP
Zhu, QS [1 ]
机构：
[1] Univ Sci & Technol China, Open Lab Bond Select Chem, Anhua 230026, Peoples R China
[2] Univ Sci & Technol China, Inst Adv Studies, Anhua 230026, Peoples R China
来源：
JOURNAL OF MOLECULAR SPECTROSCOPY | 1998年 / 192卷 / 02期
基金：
中国国家自然科学基金;
关键词：
D O I：
10.1006/jmsp.1998.7673
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
The band absorbance and line absorbance of R branch transitions are obtained from high-resolution Fourier transform measurement of silane and germane local mode overtones (n000), n = 1-5, under proper sample pressures and absorption lengths. The absorption coefficients of these overtones are derived by linear least-squares fitting. The relative intensities of overtones can be satisfactorily reproduced with the bond dipole model containing two adjustable parameters, (C) 1998 Academic Press.
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页码：249 / 256
页数：8
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