Cyclohexenones and isocoumarins from an endophytic fungus of Sarcosomataceae sp.

被引:10
作者
Tian, Jie-Feng [1 ]
Yu, Ru-Jian [2 ]
Li, Xiao-Xia [2 ]
Gao, Hao [2 ]
Hu, Dan [2 ]
Guo, Liang-Dong [3 ]
Tang, Jin-Shan [2 ]
Yao, Xin-Sheng [1 ,2 ]
机构
[1] Shenyang Pharmaceut Univ, Coll Tradit Chinese Mat Med, Shenyang 110016, Peoples R China
[2] Jinan Univ, Inst Tradit Chinese Med & Nat Prod, Coll Pharm, Guangzhou 510632, Guangdong, Peoples R China
[3] Chinese Acad Sci, Inst Microbiol, State Key Lab Mycol, Beijing 100101, Peoples R China
基金
芬兰科学院;
关键词
Sarcosomataceae sp; isocoumarin; cyclohexenone; Endophytic fungus; ABSOLUTE-CONFIGURATION; METABOLITES; MO-2(OAC)(4); DERIVATIVES; 1,2-DIOLS;
D O I
10.1080/10286020.2015.1043904
中图分类号
Q94 [植物学];
学科分类号
071001 ;
摘要
Three new cyclohexenones (1-3, named sarcosones A-C) and two new isocoumarins (4 and 5), together with five known isocoumarins (6-10), were isolated from the solid cultures of an endophytic fungus Sarcosomataceae sp. NO.49-14-2-1. Their chemical structures were elucidated by analyses of HR-ESI-TOF-MS, H-1, C-13 NMR, H-1-H-1 COSY, HSQC, and HMBC spectra. Their absolute configurations were determined via modified Mosher's method and circular dichroism spectra method.
引用
收藏
页码:550 / 558
页数:9
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