Solubility of Hybrid Halide Perovskites in DMF and DMSO

被引：32
作者：
Petrov, Andrey A. [1 ]
Ordinartsev, Artem A. [1 ]
Fateev, Sergey A. [1 ]
Goodilin, Eugene A. [1 ,2 ]
Tarasov, Alexey B. [1 ]
机构：
[1] Lomonosov Moscow State Univ, Fac Mat Sci, Lab New Mat Solar Energet, 1 Lenin Hills, Moscow 119991, Russia
[2] Lomonosov Moscow State Univ, Dept Chem, 1 Lenin Hills, Moscow 119991, Russia
来源：
MOLECULES | 2021年 / 26卷 / 24期
基金：
俄罗斯科学基金会;
关键词：
hybrid perovskites; lead halide perovskites; perovskite photovoltaics; solution processing; solubility; donor numbers; SINGLE-CRYSTALS; CRYSTALLIZATION;
D O I：
10.3390/molecules26247541
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Solution methods remain the most popular means for the fabrication of hybrid halide perovskites. However, the solubility of hybrid perovskites has not yet been quantitively investigated. In this study, we present accurate solubility data for MAPbI(3), FAPbI(3), MAPbBr(3) and FAPbBr(3) in the two most widely used solvents, DMF and DMSO, and demonstrate huge differences in the solubility behavior depending on the solution compositions. By analyzing the donor numbers of the solvents and halide anions, we rationalize the differences in the solubility behavior of hybrid perovskites with various compositions, in order to take a step forward in the search for better processing conditions of hybrid perovskites for solar cells and optoelectronics.
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页数：7
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