Bis(2-hydroxybenzoato-κO)bis[3-(4-methoxyphenyl)-4-(4-methylphenyl)-5-(2-pyridyl)-4H-1,2,4-triazole-κ2 N 1,N 5]copper(II) dihydrate

被引:2
作者
Liu, Yan [1 ]
Wang, Zuoxiang [1 ]
Zhang, Hai [1 ]
机构
[1] Southeast Univ, Sch Chem & Engn, Nanjing 211189, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词
SPIN CONVERSION; 1,2,4-TRIAZOLE; COMPLEXES;
D O I
10.1107/S1600536811016126
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title complex, [Cu(C(7)H(5)O(3))(2)(C(21)H(18)N(4)O)(2)]center dot 2H(2)O, the CuII atom is located on a centre of inversion and exists in a tetragonally distorted octahedral geometry with a CuN(4)O(2) chromophore. The intramolecular O-H...O hydrogen bond is highly strained due to the molecular geometry and, as a result, is much shorter than expected. Intermolecular C-H...O and C-H...O interactions are also observed.
引用
收藏
页码:M697 / U553
页数:10
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