Theoretical examination of reference electrodes for lithium-ion cells

被引:67
作者
Dees, Dennis W. [1 ]
Jansen, Andrew N. [1 ]
Abraham, Daniel P. [1 ]
机构
[1] Argonne Natl Lab, Argonne, IL 60439 USA
关键词
lithium; battery; electrochemical; reference; modeling;
D O I
10.1016/j.jpowsour.2007.06.128
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
An electrochemical model was developed to compare the use of internal and external reference electrodes for the study of lithium-ion cells. The impact of reference electrode placement on electrode measurements was examined using idealized reference electrodes in cells undergoing short-duration pulse currents. The effectiveness of internal reference electrodes with finite size and impedance was also examined. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:1001 / 1006
页数:6
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