Self-Assembled Organometallic Nickel Complexes as Catalysts for Selective Dimerization of Ethylene into 1-Butene

被引：35
|
作者：
Boulens, Pierre [1 ,2 ]
Pellier, Emmanuel [1 ]
Jeanneau, Erwann [3 ]
Reek, Joost N. H. [2 ]
Olivier-Bourbigou, Helene [1 ]
Breuil, Pierre-Alain R. [1 ]
机构：
[1] IFP Energies Nouvelles, Rond Point Echangeur Solaize, F-69360 Solaize, France
[2] Univ Amsterdam, van t Hoff Inst Mol Sci, Fac Sci, NL-1098 XH Amsterdam, Netherlands
[3] Ctr Diffractometrie Henri Longchambon, F-69100 Villeurbanne, France
来源：
ORGANOMETALLICS | 2015年 / 34卷 / 07期
关键词：
BIDENTATE LIGANDS; ASYMMETRIC HYDROGENATION; SUPRAMOLECULAR LIGANDS; RHODIUM(I) COMPLEXES; OLIGOMERIZATION; POLYMERIZATION; OLEFINS; COORDINATION; OPTIMIZATION; METAMORPHOS;
D O I：
10.1021/acs.organomet.5b00055
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Sulfonamido-phosphorus and aminophosphine ligands self-assemble to readily form active and stable nickel catalysts that are highly selective for the dimerization of ethylene to 1-butene. The self-assembled allyl-nickel complexes are zwitterionic and are stabilized by hydrogen bond interactions between the two ligands. These organometallic cis-diphosphine complexes rearrange under an ethylene atmosphere to give trans-diphosphine catalysts, with one monoanionic P,O METAMORPhos ligand and an aminophosphine.
引用
收藏
页码：1139 / 1142
页数：4
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