Self-Assembled Organometallic Nickel Complexes as Catalysts for Selective Dimerization of Ethylene into 1-Butene

被引：35

作者：

Boulens, Pierre ^{[1
,2
]}

Pellier, Emmanuel ^{[1
]}

Jeanneau, Erwann ^{[3
]}

Reek, Joost N. H. ^{[2
]}

Olivier-Bourbigou, Helene ^{[1
]}

Breuil, Pierre-Alain R. ^{[1
]}

机构：

[1] IFP Energies Nouvelles, Rond Point Echangeur Solaize, F-69360 Solaize, France

[2] Univ Amsterdam, van t Hoff Inst Mol Sci, Fac Sci, NL-1098 XH Amsterdam, Netherlands

[3] Ctr Diffractometrie Henri Longchambon, F-69100 Villeurbanne, France

来源：

ORGANOMETALLICS | 2015年 / 34卷 / 07期

关键词：

BIDENTATE LIGANDS; ASYMMETRIC HYDROGENATION; SUPRAMOLECULAR LIGANDS; RHODIUM(I) COMPLEXES; OLIGOMERIZATION; POLYMERIZATION; OLEFINS; COORDINATION; OPTIMIZATION; METAMORPHOS;

D O I：

10.1021/acs.organomet.5b00055

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Sulfonamido-phosphorus and aminophosphine ligands self-assemble to readily form active and stable nickel catalysts that are highly selective for the dimerization of ethylene to 1-butene. The self-assembled allyl-nickel complexes are zwitterionic and are stabilized by hydrogen bond interactions between the two ligands. These organometallic cis-diphosphine complexes rearrange under an ethylene atmosphere to give trans-diphosphine catalysts, with one monoanionic P,O METAMORPhos ligand and an aminophosphine.

引用

页码：1139 / 1142

页数：4

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