One-step hydrothermal synthesis of amorphous CoMoS4/N-rGO nanocomposites as anode materials with improved cyclability for sodium-ion batteries

被引:7
|
作者
Zhu, Yaqin [1 ]
Zhao, Jiachang [1 ]
Chen, Jiajun [2 ]
Xu, Jingli [1 ]
机构
[1] Shanghai Univ Engn Sci, Coll Chem & Chem Engn, Shanghai 201620, Peoples R China
[2] Pegasus Power Energy Co Ltd, Hangzhou 310019, Peoples R China
基金
中国国家自然科学基金;
关键词
Amorphous structure; Anode materials; CoMoS4; N-doped reduced graphene oxide; Sodium-ion batteries; GRAPHENE OXIDE NANOCOMPOSITES; CARBON NANOSHEETS; MOS2; NANOSHEETS; RATE CAPABILITY; PERFORMANCE; STORAGE; NANOPARTICLES; NANOFIBERS; ELECTRODES; CATALYSTS;
D O I
10.1007/s10800-020-01409-0
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The amorphous CoMoS4/N-rGO nanocomposites can be synthesized by a simple one-step hydrothermal method as anode materials for sodium-ion batteries (SIBs). Since amorphous structure can provide more ion diffusion transport channels, nitrogen-doped reduced graphene oxide (N-rGO) has high electrical conductivity and also behaves as a buffer to adapt to the volume change of CoMoS4. CoMoS4/N-rGO exhibits enhanced electrochemical performance compared with single CoMoS4. After 100 cycles, CoMoS4/N-rGO has a discharge specific capacity of 414.9 mAh g(-1) at a current density of 0.1 A g(-1), which is 85% of the initial capacity. In addition, CoMoS4/N-rGO exhibits good rate performance with a specific capacity of 305.5 mAh g(-1) at 2 A g(-1). CoMoS4/N-rGO nanocomposites will be promising anode materials for SIBs due to their excellent electrochemical properties. [GRAPHICS] .
引用
收藏
页码:513 / 522
页数:10
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