Heterogeneous Catalysis on Metal Oxides

被引:363
作者
Vedrine, Jacques C. [1 ]
机构
[1] Univ P & M Curie, Lab Reactivite Surface, Sorbonne Univ, UMR CNRS 7197, 4 Pl Jussieu, F-75252 Paris, France
关键词
metal oxide catalysts; heterogeneous catalysis; main catalytic reactions; main catalytic processes; SELECTIVE OXIDATION CATALYSIS; STRUCTURE-SENSITIVITY; SURFACE-CHEMISTRY; CRYSTAL-CHEMISTRY; ACTIVE-CENTERS; ACID SITES; PROPANE; PHOTOCATALYSIS; DEHYDROGENATION; AMMOXIDATION;
D O I
10.3390/catal7110341
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This review article contains a reminder of the fundamentals of heterogeneous catalysis and a description of the main domains of heterogeneous catalysis and main families of metal oxide catalysts, which cover acid-base reactions, selective partial oxidation reactions, total oxidation reactions, depollution, biomass conversion, green chemistry and photocatalysis. Metal oxide catalysts are essential components in most refining and petrochemical processes. These catalysts are also critical to improving environmental quality. This paper attempts to review the major current industrial applications of supported and unsupported metal oxide catalysts. Viewpoints for understanding the catalysts' action are given, while applications and several case studies from academia and industry are given. Emphases are on catalyst description from synthesis to reaction conditions, on main industrial applications in the different domains and on views for the future, mainly regulated by environmental issues. Following a review of the major types of metal oxide catalysts and the processes that use these catalysts, this paper considers current and prospective major applications, where recent advances in the science of metal oxide catalysts have major economic and environmental impacts.
引用
收藏
页数:25
相关论文
共 97 条
  • [81] Multiconfiguration Self-Consistent Field and Multireference Configuration Interaction Methods and Applications
    Szalay, Peter G.
    Mueller, Thomas
    Gidofalvi, Gergely
    Lischka, Hans
    Shepard, Ron
    [J]. CHEMICAL REVIEWS, 2012, 112 (01) : 108 - 181
  • [82] A theory of the catalytic surface
    Taylor, HS
    [J]. PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-CONTAINING PAPERS OF A MATHEMATICAL AND PHYSICAL CHARACTER, 1925, 108 (745) : 105 - 111
  • [83] Thomas JM., 2014, Principles and Practice of Heterogeneous Catalysis, V2nd
  • [84] The societal significance of catalysis and the growing practical importance of single-site heterogeneous catalysts
    Thomas, John Meurig
    [J]. PROCEEDINGS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES, 2012, 468 (2143): : 1884 - 1903
  • [85] Thursfield A., 2006, DEFECT CHEM TRANSPOR, P55
  • [86] Activation of propane and butanes over niobium- and tantalum-based oxide catalysts
    Ushikubo, T
    [J]. CATALYSIS TODAY, 2003, 78 (1-4) : 79 - 84
  • [87] Ammoxidation of propane over Mo-V-Nb-Te mixed oxide catalysts
    Ushikubo, T
    Oshima, K
    Kayou, A
    Hatano, M
    [J]. SPILLOVER AND MIGRATION OF SURFACE SPECIES ON CATALYSTS, 1997, 112 : 473 - 480
  • [88] Ushikubo T, 1993, US Patent, Patent No. [5231214A, 5231214]
  • [89] Vedrine J. C., 2017, HETEROGENEOUS CATALY
  • [90] Heterogeneous catalytic partial oxidation of lower alkanes (C1 - C6) on mixed metal oxides
    Vedrine, Jacques C.
    [J]. JOURNAL OF ENERGY CHEMISTRY, 2016, 25 (06) : 936 - 946