Hydrogen-induced changes of the microscopic structure of microcrystalline silicon

被引:1
作者
Kaiser, I [1 ]
Nickel, NH [1 ]
Pilz, W [1 ]
Fuhs, W [1 ]
机构
[1] Hahn Meitner Inst Kernforsch Berlin GmbH, D-12489 Berlin, Germany
来源
HYDROGEN IN SEMICONDUCTORS AND METALS | 1998年 / 513卷
关键词
D O I
10.1557/PROC-513-393
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Microcrystalline silicon samples were exposed to an electron cyclotron resonance (ECR) hydrogen plasma at various exposure times and substrate temperatures. Before and after each post-hydrogenation treatment the crystalline fraction, X-C, was determined from Raman backscattering spectra. The results reveal that the change of X-C strongly depends on the structural composition of the starting material. Amorphous samples exhibit an increase of X-C while for mu c-Si specimens the X-C decreases. The decrease of X-C is enhanced for specimens with a high initial crystalline fraction. The same plasma treatment of Si-wafers did not lead to amorphisation. We conclude that the presence of lattice strain is required to observe a H-induced decrease of X-C.
引用
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页码:393 / 398
页数:6
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