Growth, optical, thermal and laser damage threshold studies of 4-aminopyridinium 4-nitrophenolate 4-nitrophenol crystal

被引:26
作者
Jagadesan, A. [1 ]
Peramaiyan, G. [2 ]
Kumar, R. Mohan [3 ]
Arjunan, S. [1 ]
机构
[1] RMK Engn Coll, Dept Phys, Madras 601206, Tamil Nadu, India
[2] Vel Tech Univ, Madras 600062, Tamil Nadu, India
[3] Presidency Coll, Dept Phys, Madras 600005, Tamil Nadu, India
关键词
Growth from solutions; Organic compounds; Nonlinear optical materials; Nonlinear optical; ASSEMBLIES; DESIGN;
D O I
10.1016/j.jcrysgro.2015.02.069
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
Organic nonlinear optical (NLO) single crystals of 4-aminopyriclinium 4-nitrophenolate 4-nitrophenol (4AP4NP) were grown by the slow evaporation solution growth technique. The unit cell parameters and space group of 4AP4NP crystal were found out by single crystal X-ray diffraction analysis. From the UV-vis-NIR spectral studies, the lower cut-off wavelength of the grown crystal was found to be 474 nm. The laser damage threshold study shows that 4AP4NP crystal withstands the laser radiation up to 3.67 GW cm(-2). Thermogravimetric and differential thermal analyses revealed that 4AP4ANP is thermally stable up to 175 degrees C. The specific heat capacity of 4AP4NP was measured to be 3.9135 J g(-1) K-1 at 33 degrees C. Kurtz and Perry powder study reveals that 4AP4NP is a phase-matchable NLO material. The four independent tensor coefficients of dielectric permittivity were found to be epsilon(11) =25.09, epsilon(22) = 25.84, epsilon(33) = 26.69 and epsilon(13) = 0.8 from the dielectric measurement. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:153 / 157
页数:5
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