Anionic polymerization of long-chain alkyl methacrylates

被引：0
|
作者：
Mishra, MK [1 ]
Bradley, J [1 ]
Saxton, RG [1 ]
Duggal, A [1 ]
机构：
[1] Ethyl Corp Res Ctr, Richmond, VA 23218 USA
来源：
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2001年 / 39卷 / 06期
关键词：
anionic; polymerization; alkyl methacrylates; lauryl methacrylate; cetyleicosyl methacrylate (CEMA);
D O I：
10.1002/1099-0518(20010315)39:6<947::AID-POLA1069>3.0.CO;2-G
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Anionic polymerization of higher alkyl methacrylates was investigated. Polymerization was performed in a jacketed glass-resin kettle under a nitrogen atmosphere at -30 °C. Gel permeation chromatography (GPC) and weighing of the dried polymer after precipitation in a nonsolvent, were used to determine monomer conversion ratios. Fast addition of the monomers produced lower molecular weight distribution (MWD) polymers than slow addition processes.
引用
收藏
页码：947 / 950
页数：4
相关论文
共 50 条
  • [41] SYNTHESIS OF LABELLED LONG-CHAIN CHOLESTEROL ALKYL ETHERS
    PALTAUF, F
    MONATSHEFTE FUR CHEMIE, 1968, 99 (04): : 1277 - &
  • [42] ANIONIC SYNTHESIS AND CHARACTERIZATION OF VARIOUS POLY(ALKYL METHACRYLATES)
    LONG, TE
    SUBRAMANIAN, R
    WARD, TC
    MCGRATH, JE
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1986, 192 : 225 - POLY
  • [43] EFFECT OF THE SIZE OF THE ALKYL SUBSTITUENT ON CATALYSIS OF THE CHAIN TRANSFER TO MONOMER IN RADICAL POLYMERIZATION OF NORMAL-ALKYL METHACRYLATES
    MIRONYCHEV, VY
    MOGILEVICH, MM
    SMIRNOV, BR
    SHAPIRO, YY
    GOLIKOV, IV
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1986, 28 (09): : 1891 - 1894
  • [44] Living, syndioselective polymerization of alkyl methacrylates by a titanium alkyl cation
    Chen, EYX
    Mariott, WR
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2004, 227 : U374 - U375
  • [45] ELECTRON CRYSTALLOGRAPHY OF ALKYL CHAIN LIPIDS - IDENTIFICATION OF LONG-CHAIN PACKING
    DORSET, DL
    ULTRAMICROSCOPY, 1984, 12 (1-2) : 19 - 28
  • [46] VINYL POLYMERIZATION .79. EFFECT OF ALKYL GROUP ON RADICAL POLYMERIZATION OF ALKYL METHACRYLATES
    OTSU, T
    ITO, T
    IMOTO, M
    JOURNAL OF POLYMER SCIENCE PART A-GENERAL PAPERS, 1964, 2 (6PA): : 2901 - &
  • [47] PREPARATION OF LONG-CHAIN TERTIARY MONOALCOHOLS VIA ANIONIC PROCESS
    RODRIGUEZ, F
    ABADIE, M
    SCHUE, F
    EUROPEAN POLYMER JOURNAL, 1976, 12 (01) : 23 - 24
  • [48] Anionic polymerization of fluorine-substituted phenyl methacrylates
    Bin Li
    Pan Zhou
    Yuefei Chen
    Biao Jiang
    Hongping Zhu
    Science China(Chemistry), 2015, (01) : 107 - 113
  • [49] ORGANOALUMINUM COMPOUNDS AS INITIATORS OF ANIONIC-POLYMERIZATION OF METHACRYLATES
    MILOVSKAYA, EB
    MAKARYCHEVMIKHAILOV, MN
    SKVORTSEVICH, EP
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1975, 17 (06): : 1217 - 1222
  • [50] EFFECTS OF LONG-CHAIN BRANCHING ON DISTRIBUTION OF DEGREE OF POLYMERIZATION
    SMALL, PA
    POLYMER, 1972, 13 (11) : 536 - &
12345