Anionic polymerization of long-chain alkyl methacrylates

被引：0
|
作者：
Mishra, MK [1 ]
Bradley, J [1 ]
Saxton, RG [1 ]
Duggal, A [1 ]
机构：
[1] Ethyl Corp Res Ctr, Richmond, VA 23218 USA
来源：
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY | 2001年 / 39卷 / 06期
关键词：
anionic; polymerization; alkyl methacrylates; lauryl methacrylate; cetyleicosyl methacrylate (CEMA);
D O I：
10.1002/1099-0518(20010315)39:6<947::AID-POLA1069>3.0.CO;2-G
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Anionic polymerization of higher alkyl methacrylates was investigated. Polymerization was performed in a jacketed glass-resin kettle under a nitrogen atmosphere at -30 °C. Gel permeation chromatography (GPC) and weighing of the dried polymer after precipitation in a nonsolvent, were used to determine monomer conversion ratios. Fast addition of the monomers produced lower molecular weight distribution (MWD) polymers than slow addition processes.
引用
收藏
页码：947 / 950
页数：4
相关论文
共 50 条
  • [1] Microflow System Controlled Anionic Polymerization of Alkyl Methacrylates
    Nagaki, Aiichiro
    Tomida, Yutaka
    Miyazaki, Atsuo
    Yoshida, Jun-ichi
    MACROMOLECULES, 2009, 42 (13) : 4384 - 4387
  • [2] ANIONIC-POLYMERIZATION OF ALKYL METHACRYLATES IN THE PRESENCE OF DIETHYLZINC
    OZAKI, H
    HIRAO, A
    NAKAHAMA, S
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 1995, 196 (07) : 2099 - 2111
  • [3] Anionic polymerization of alkyl methacrylates using flow microreactor systems
    Nagaki, Aiichiro
    Miyazaki, Atsuo
    Tomida, Yutaka
    Yoshida, Jun-ichi
    CHEMICAL ENGINEERING JOURNAL, 2011, 167 (2-3) : 548 - 555
  • [4] New plurifunctional initiators for anionic polymerization of alkyl methacrylates.
    Hubert, C
    Gnanou, Y
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1997, 213 : 15 - POLY
  • [5] EXTRACTION OF NEUTRAL AND ANIONIC COMPLEXES OF NITROSYLRUTHENIUM BY LONG-CHAIN ALKYL AMINES
    LLOYD, PJ
    JOURNAL OF THE SOUTH AFRICAN CHEMICAL INSTITUTE, 1967, 20 (02): : 174 - &
  • [6] POLY 160-High temperature anionic polymerization of alkyl methacrylates
    Huyck, Rebecca H.
    Long, Timothy E.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2008, 235
  • [7] SOLID-STATE POLYMERIZATION OF LONG-CHAIN VINYL COMPOUNDS .4. EFFECTS OF CHAIN-LENGTH ON THE POLYMORPHIC BEHAVIOR AND POST-POLYMERIZATION OF N-ALKYL METHACRYLATES
    SHIBASAKI, Y
    FUKUDA, K
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1980, 18 (08) : 2437 - 2449
  • [8] ANIONIC POLYMERIZATION OF ALKYL METHACRYLATES INITIATED BY nBuCu(NCy2)Li
    Han, Bing-yong
    Liang, Jian-guo
    Lu, Jian-min
    An, Feng
    Yang, Wan-tai
    CHINESE JOURNAL OF POLYMER SCIENCE, 2009, 27 (03) : 427 - 433
  • [9] EFFECTS OF LONG-CHAIN ALKYL PEROXYDICARBONATES ON THE PROPERTIES OF PVC PRODUCED BY SUSPENSION POLYMERIZATION
    ARSLANALP, C
    ERBAY, E
    BILGIC, T
    SAVASCI, OT
    ANGEWANDTE MAKROMOLEKULARE CHEMIE, 1991, 193 : 99 - 112
  • [10] ANIONIC POLYMERIZATION OF ALKYL METHACRYLATES INITIATED BY nBuCu(NCy2)Li
    韩丙勇
    杨万泰
    Chinese Journal of Polymer Science, 2009, 27 (03) : 427 - 433
12345