A highly efficient heterogeneous copper-catalyzed Chan-Lam coupling reaction of sulfonyl azides with arylboronic acids leading to N-arylsulfonamides

被引：26
|
作者：
You, Chongren [1 ]
Yao, Fang [2 ]
Yan, Tao [1 ]
Cai, Mingzhong [1 ]
机构：
[1] Jiangxi Normal Univ, Coll Chem & Chem Engn, Minist Educ, Key Lab Funct Small Organ Mol, Nanchang 330022, Peoples R China
[2] Quzhou Univ, Coll Chem & Mat Engn, Quzhou 324000, Peoples R China
来源：
RSC ADVANCES | 2016年 / 6卷 / 49期
基金：
中国国家自然科学基金;
关键词：
MESOPOROUS MOLECULAR-SIEVES; C-H AMIDATION; CLICK CHEMISTRY; BORONIC ACIDS; RECYCLABLE CATALYST; ARYL HALIDES; SULFONAMIDES; ARYLATION; ALCOHOLS; COMPLEX;
D O I：
10.1039/c6ra04298h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A heterogeneous Chan-Lam coupling reaction between sulfonyl azides and arylboronic acids was achieved in MeOH at room temperature in the presence of 10 mol% of an L-proline-functionalized MCM-41-immobilized copper(I) complex [MCM-41-L-proline-CuCl] under air, yielding a variety of N-arylsulfonamides in excellent yields. The new heterogeneous copper complex can be prepared from commercially readily available and inexpensive reagents, and recovered by simple filtration of the reaction solution and recycled at least 8 times without any decreases in activity.
引用
收藏
页码：43605 / 43612
页数：8
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