Re-examination of martensitic stabilization in Cu-based shape memory alloys Part II. Key factors determining occurrence of martensitic stabilization in Cu-based alloys

Present proposed mechanisms for ageing-induced martensitic stabilization cannot explain why the amount of martensites losing reverse transformation ability (RTA) positively depended on Ms temperatures in directly-quenched CuZnAl alloys owing to dynamic ageing during the cooling process of quenching and subsequent slow heating. We proposed and confirmed that the number of vacancies at martensites boundaries (N-vmb) was the key factor controlling the occurrence of martensitic stabilization and its resulting RTA or loss in shape memory effect, not the number of vacancies inside the martensites and their long-range diffusion. All reported results can be rationalized by the positive dependence of original N-vmb on the Ms temperature. (C) 2022 Published by Elsevier B.V.