Thermochemistry of solvated crystals of C60 and C70 with o-xylene

被引：6

作者：

Avramenko, NV ^{[1
]}

Mirakyan, AL ^{[1
]}

Korobov, MV ^{[1
]}

Stukalin, EB ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 1998年 / 52卷 / 03期

关键词：

DSC; fullerenes; solubility; solvated crystals;

D O I：

10.1023/A:1010179027071

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Differential scanning calorimetry (DSC) was used to study the binary systems of C-60-o-xylene and C-70-o-xylene and the ternary system C-60-C-70-o-xylene. Fullerene C-60 formed solvated crystals C-60.2C(8)H(10) with incongruent melting point 320 K and with enthalpy of decomposition 31+/-3 kJ (mol of C-60)(-1). Two solvated crystals of C-70 with incongruent melting points 283 and 369 K, and with decomposition enthalpies 18.5+/-2.2 and 23.0+/-1.5 kJ (mol of C-70)(-1), were formed from o-xylene solutions. Three ternary compositions with C-60/C-70 mole ratios of 3:1, 1:1 and 1:3 were scanned by DSC.

引用

页码：831 / 836

页数：6

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