Synthesis and applications of a new class of C2 symmetric phosphorus donor ligand for asymmetric catalysis.

被引：26

作者：

Brenchley, G

Fedouloff, M

Merifield, E

Wills, M

机构：

[1] UNIV WARWICK,DEPT CHEM,COVENTRY CV4 7AL,W MIDLANDS,ENGLAND

[2] SMITHKLINE BEECHAM PHARMACEUT,HARLOW CM19 5AW,ESSEX,ENGLAND

来源：

TETRAHEDRON-ASYMMETRY | 1996年 / 7卷 / 10期

关键词：

D O I：

10.1016/0957-4166(96)00368-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel class of C2-symmetric ligand has been prepared using an intramolecular cyclisation reaction of a diazaphosphole borane complex, Preliminary results of its application to the asymmetric catalysis of hydrogenation, hydrosilylation and allylic substitution reactions are described. Copyright (C) 1996 Elsevier Science Ltd

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页码：2809 / 2812

页数：4

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