A flash photolysis and theoretical study of the reaction of arylnitroso oxides with phosphorus(III) compounds

被引：3

作者：

Khursan, V. S. ^{[1
]}

Kovaleva, O. A. ^{[1
]}

Chainikova, E. M. ^{[1
]}

Talipov, M. R. ^{[1
]}

Safiullin, R. L. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Organ Chem, Ufa Sci Ctr, Ufa 450054, Russia

来源：

HIGH ENERGY CHEMISTRY | 2010年 / 44卷 / 04期

基金：

俄罗斯基础研究基金会;

关键词：

Phosphine; Phosphite; Triphenylphosphine; Lone Electron Pair; High Energy Chemistry;

D O I：

10.1134/S0018143910040053

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The kinetic features of the reaction of aromatic nitroso oxides (ArNOO) with tri-n-butyl phosphite and substituted phosphines were studied by flash photolysis. It was shown that the trans-isomers of nitroso oxides enter into the reaction. The mechanism of the reaction was studied by theoretical methods, and the inertness of the cis-form of ArNOO was explained.

引用

页码：284 / 289

页数：6

共 5 条

[1] A flash photolysis and theoretical study of the reaction of arylnitroso oxides with phosphorus(III) compounds
V. S. Khursan
O. A. Kovaleva
E. M. Chainikova
M. R. Talipov
R. L. Safiullin
High Energy Chemistry, 2010, 44 : 284 - 289
[2] Flash photolysis study of the reactivity of isomeric forms of arylnitroso oxides toward triphenyl phosphite
V. S. Khursan
E. M. Chainikova
R. L. Safiullin
High Energy Chemistry, 2009, 43 : 467 - 470
[3] Theoretical study on the reaction between phosphacyclopropenylidene and ethylene: An alternative approach to the formation of phosphorus-bearing heterocyclic compounds
Wu, Mengyao
Wang, Yilin
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Gu, Jinsong
JOURNAL OF THE SERBIAN CHEMICAL SOCIETY, 2020, 85 (09) : 1175 - 1184
[4] EXPERIMENTAL AND THEORETICAL STUDY OF STABLE PHOSPHORUS YLIDES DERIVED FROM INDAZOLE IN THE PRESENCE OF DIFFERENT DIALKYL ACETYELENEDICARBOXYLATES: FURTHER INSIGHTS INTO THE REACTION MECHANISM
Zakarianezhad, Mohammad
Makiabadi, Batoul
Shool, Motahare
JOURNAL OF THE CHILEAN CHEMICAL SOCIETY, 2016, 61 (02): : 2929 - 2934
[5] Synthesis and dynamic 1H NMR study around the carbon-carbon double bond in the new stable phosphorus ylides derived from the reaction between hexamethyl phosphorous triamide and dimethyl acetylenedicarboxylate in the presence of NH-heterocyclic compounds
Ziyaadini, Morteza
Maghsoodlou, Malek Taher
Hazeri, Nourollah
Habibi-Khorassani, Sayyed Mostafa
HETEROATOM CHEMISTRY, 2012, 23 (02) : 131 - 137

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