Synthesis and electrical properties of CuNi0.5Ti0.5O2

被引:10
作者
Marquardt, MA [1 ]
Cann, DP [1 ]
机构
[1] Iowa State Univ, Dept Mat Sci & Engn, Ames, IA 50011 USA
关键词
delafossite; electroceramics; electrical properties;
D O I
10.1016/j.matlet.2005.07.089
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
This paper presents structural and electrical data on the delafossite compound CuNi0.5Ti0.5O2, Ceramics of CuNi0.5Ti0.5O2 Were prepared via solid state synthesis techniques in a controlled atmosphere of pO(2) = 10(-3) atm. The compound crystallized into the 3R delafossite phase with hexagonal lattice parameters of a = 3.0079 (+/- 0.0004) angstrom and c = 17.2543 (+/- 0.003) angstrom. The electrical properties of the material are characterized by a room temperature conductivity of 2 x 10(-6) S/cm. The conductivity exhibits an Arrhenius-like temperature dependence with an activation energy of 0.48 eV. (C) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:81 / 85
页数:5
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