Using Host-Guest Complexation to Fold a Flexible Linear Organic String: Kinetically Controlled Syntheses of [3]Catenanes and a Five-Membered Molecular Necklace

被引：19

作者：

Chang, Chia-Fong ^{[1
]}

Chuang, Chun-Ju ^{[1
]}

Lai, Chien-Chen ^{[2
,3
]}

Liu, Yi-Hung ^{[1
]}

Peng, Shie-Ming ^{[1
]}

Chiu, Sheng-Hsien ^{[1
]}

机构：

[1] Natl Taiwan Univ, Dept Chem, Taipei 10617, Taiwan

[2] Natl Chung Hsing Univ, Inst Mol Biol, Taichung 40227, Taiwan

[3] China Med Univ, Grad Inst Chinese Med Sci, Taichung, Taiwan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 40期

关键词：

catenanes; macrocyclizations; molecular necklaces; molecular recognition; template synthesis; TEMPLATE-DIRECTED SYNTHESIS; RING-CLOSURE REACTIONS; ROTAXANE; DELIVERY; CHLORIDE; SALTS;

D O I：

10.1002/anie.201205498

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rings and necklaces: Three [3]catenanes and a five-membered molecular necklace ([5]MN), with up to 60- and 92-membered rings as their centerpieces, respectively, have been synthesized. The synthesis started from the corresponding complexes in which the threaded flexible linear guests were bent at approximately right angles to facilitate kinetically controlled macrocyclizations. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：10094 / 10098

页数：5

共 62 条

[1]

Adeli M, 2011, J MATER CHEM, V21, P18686, DOI [10.1039/c1jm14252f, 10.1039/c1jm12412a]

[2]

Amabilino D.B, 1997, ANGEW CHEM, V109, P2160

[3] Oligocatenanes made to order [J].

Amabilino, DB ;

Ashton, PR ;

Balzani, V ;

Boyd, SE ;

Credi, A ;

Lee, JY ;

Menzer, S ;

Stoddart, JF ;

Venturi, M ;

Williams, DJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (18) :4295-4307

[4] The five-stage self-assembly of a branched heptacatenane [J].

Amabilino, DB ;

Ashton, PR ;

Boyd, SE ;

Lee, JY ;

Menzer, S ;

Stoddart, JF ;

Williams, DJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (19) :2070-2072

[5] Snap-Top Nanocarriers [J].

Ambrogio, Michael W. ;

Pecorelli, Travis A. ;

Patel, Kaushik ;

Khashab, Niveen M. ;

Trabolsi, All ;

Khatib, Hussam A. ;

Botros, Youssry Y. ;

Zink, Jeffrey I. ;

Stoddarrt, J. Fraser .

ORGANIC LETTERS, 2010, 12 (15) :3304-3307

[6]

[Anonymous], 2010, ANGEW CHEM

[7] Pseudorotaxanes formed between secondary dialkylammonium salts and crown ethers [J].

Ashton, PR ;

Chrystal, EJT ;

Glink, PT ;

Menzer, S ;

Schiavo, C ;

Spencer, N ;

Stoddart, JF ;

Tasker, PA ;

White, AJP ;

Williams, DJ .

CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (06) :709-728

[8] Hammett correlations 'beyond the molecule' [J].

Ashton, PR ;

Fyfe, MCT ;

Hickingbottom, SK ;

Stoddart, JF ;

White, AJP ;

Williams, DJ .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1998, (10) :2117-2128

[9] The template-directed synthesis of cyclobis(paraquat-4,4'-biphenylene) [J].

Ashton, PR ;

Menzer, S ;

Raymo, FM ;

Shimizu, GKH ;

Stoddart, JF ;

Williams, DJ .

CHEMICAL COMMUNICATIONS, 1996, (04) :487-490

[10] Storable, thermally activated, near-infrared chemiluminescent dyes and dye-stained microparticles for optical imaging [J].

Baumes, Jeffrey M. ;

Gassensmith, Jeremiah J. ;

Giblin, Jay ;

Lee, Jung-Jae ;

White, Alexander G. ;

Culligan, William J. ;

Leevy, W. Matthew ;

Kuno, Masaru ;

Smith, Bradley D. .

NATURE CHEMISTRY, 2010, 2 (12) :1025-1030

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