Photoelectrocatalytic degradation of recalcitrant organic pollutants using TiO2 film electrodes: An overview

被引:143
作者
Zhang, Yanzong [1 ]
Xiong, Xiaoyan [1 ]
Han, Yue [1 ]
Zhang, Xiaohong [1 ]
Shen, Fei [1 ]
Deng, Shihuai [1 ]
Xiao, Hong [1 ]
Yang, Xinyao [1 ]
Yang, Gang [1 ]
Peng, Hong [1 ]
机构
[1] Sichuan Agr Univ, Coll Resources & Environm, Prov Key Lab Agr Environm Engn, Chengdu 611130, Sichuan, Peoples R China
关键词
Anodic oxidation; Atomic layer deposition; TiO2 nanotube array electrodes; Doping; Potential bias; Kinetic model; CHEMICAL-VAPOR-DEPOSITION; ELECTROCHEMICAL-ASSISTED PHOTODEGRADATION; TIO2-ASSISTED PHOTOCATALYTIC DEGRADATION; NANOTUBE ARRAYS ELECTRODE; ATOMIC LAYER DEPOSITION; THIN-FILMS; AQUEOUS-SOLUTION; RHODAMINE-B; ANODIC-OXIDATION; VISIBLE-LIGHT;
D O I
10.1016/j.chemosphere.2012.03.020
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Photoelectrocatalytic (PEC) technology involved applying an electrical bias to a TiO2 film electrode, has been widely applied to the degradation of refractory organic pollutants, owing to its high degradation efficiency. This paper reviews recent developments in the PEC degradation of recalcitrant organic contaminants using a TiO2 film electrode. The preparation and application of various TiO2 film electrodes have been investigated, as well as the parameters that influence PEC activity such as the crystal structure, the film thickness and substrate material, the applied electrical bias, the solution pH and conductivity. The improvement of PEC activity by doping the TiO2 film electrode with metal and non-metal ions has been discussed. The mechanism and kinetics for the PEC degradation of organic pollutants have also been highlighted. (C) 2012 Elsevier Ltd. All rights reserved.
引用
收藏
页码:145 / 154
页数:10
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