Simulation of radiation-chemical behavior of americium in perchloric acid.: I.: 0.1-4 M HClO4

被引：0

作者：

Vladimirova, MV ^{[1
]}

机构：

[1] Bochvar All Russia Res Inst Inorgan Mat, State Sci Ctr, Moscow, Russia

来源：

RADIOCHEMISTRY | 1999年 / 41卷 / 01期

关键词：

D O I：

暂无

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Simulation of radiation-chemical reduction of Am(VI) and Am(V) in 0.1-4 M HClO4 was carried out. As a result of simulation and comparison of the calculated and experimental data, an optimum scheme of radiation-chemical reactions was developed, unknown reaction constants were found, and the rate-determining stages of individual valence transitions of americium under these conditions were elucidated.

引用

页码：50 / 58

页数：9

共 17 条

[1] Simulation of radiation-chemical behavior of americium in perchloric acid.: II.: 6-12 M HClO4
Vladimirova, MV
RADIOCHEMISTRY, 1999, 41 (01) : 59 - 67
[2] MATHEMATICAL SIMULATION OF THE RADIATION-CHEMICAL PROCESSES IN HCLO4 SOLUTIONS
VLADIMIROVA, MV
HIGH ENERGY CHEMISTRY, 1995, 29 (05) : 304 - 309
[3] Simulation of Radiation-Chemical Behavior of Neptunium in Perchloric Acid. I. Reduction of Np(VI) and Oxidation of Np(V)
Vladimirova, M. V.
Radiokhimiya, 39 (03):
[4] MATHEMATICAL-MODELING OF RADIATION-CHEMICAL PROCESSES IN HCLO4
VLADIMIROVA, MV
RADIATION PHYSICS AND CHEMISTRY, 1995, 46 (4-6): : 575 - 578
[5] RADIATION-CHEMICAL BEHAVIOR OF RH(IV) IN HCLO4 AND HNO3 SOLUTIONS
VLADIMIROVA, MV
KHALKINA, EV
RADIOCHEMISTRY, 1994, 36 (05) : 500 - 505
[6] Mathematical Modeling of the Radiation-Chemical Oxidation of U(IV) in HClO4
Vladimirova, M. V.
Radiokhimiya, 37 (05):
[7] MATHEMATICAL-MODELING OF THE RADIATION-CHEMICAL OXIDATION OF U(IV) IN HCLO4
VLADIMIROVA, MV
RADIOCHEMISTRY, 1995, 37 (05) : 422 - 428
[8] Ionization of perchloric acid in solutions of composition HClO4 : H2O : Bu4NClO4=1 : 1 : m
Karelin, AI
Nikitina, ZK
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2002, 47 (01) : 129 - 138
[9] Preparation and electrochemical characterization of palladium single crystal electrodes in 0.1 M H2SO4 and HClO4 part I.: Low-index phases
Hara, M.
Linke, U.
Wandlowski, Th.
ELECTROCHIMICA ACTA, 2007, 52 (18) : 5733 - 5748
[10] Simulation of radiation-chemical behavior of neptunium in perchloric acid .2. Oxidation of Np(IV) and reduction of Np(V)
Vladimirova, MV
RADIOCHEMISTRY, 1997, 39 (03) : 260 - 268

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