Flexible and Conductive 3D Printable Polyvinylidene Fluoride and Poly(N,N-dimethylacrylamide) Based Gel Polymer Electrolytes

被引：18
|
作者：
Rahman, Md Sazzadur [1 ]
Shiblee, M. D. Nahin Islam [1 ]
Ahmed, Kumkum [2 ]
Khosla, Ajit [1 ]
Ogawa, Jun [1 ]
Kawakami, Masaru [1 ]
Furukawa, Hidemitsu [1 ]
机构：
[1] Yamagata Univ, Grad Sch Sci & Engn, Dept Mech Syst Engn, Soft & Wet Matter Engn Lab SWEL, 4-3-16 Jonan, Yonezawa, Yamagata 9928510, Japan
[2] Shibaura Inst Technol, Coll Engn, 3 Chome 7-5 Toyosu, Koto City, Tokyo 1358548, Japan
来源：
MACROMOLECULAR MATERIALS AND ENGINEERING | 2020年 / 305卷 / 09期
基金：
日本科学技术振兴机构; 日本学术振兴会;
关键词：
3D printing; crosslinked gels; flexible; gel polymer electrolyte; ionic conductivity; BATTERY;
D O I：
10.1002/mame.202000262
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
In this work, 3D printable gel polymer electrolytes (GPEs) based onN,N-dimethylacrylamide (DMAAm) and polyvinylidene fluoride (PVDF) in lithium chloride containing ethylene glycol solution are synthesized and their physicochemical properties are investigated. 3D printing is carried out with a customized stereolithography type 3D gel printer named "Soft and Wet Intelligent Matter-Easy Realizer" and free forming GPE samples having variable shapes and sizes are obtained. Printed PVDF/PDMAAm-based GPEs exhibit tunable mechanical properties and favorable thermal stability. Electrochemical proprieties of the printed GPEs are carried out via impedance spectroscopy in the temperature range of 25-90 degrees C by varying PVDF content. Ionic conductivity as high as 6.5 x 10(-4)S cm(-1)is achieved at room temperature for GPE containing low PVDF content (5 wt%) and conductivity of the GPEs is increased as temperature rises.
引用
收藏
页数：8
相关论文
共 50 条
  • [41] Robust, recoverable poly(N,N-dimethylacrylamide)-based hydrogels crosslinked by vinylated chitosan with recyclable adsorbability for acid red
    Wang, Xiaoning
    Xing, Yacheng
    Zhao, Xihui
    Ji, Quan
    Xia, Yanzhi
    Ma, Xiaomei
    JOURNAL OF APPLIED POLYMER SCIENCE, 2019, 136 (20)
  • [42] Influence of Macromolecular Architecture on the Optical and Humidity-Sensing Properties of Poly(N,N-Dimethylacrylamide)-Based Block Copolymers
    Lazarova, Katerina
    Vasileva, Marina
    Ivanova, Sijka
    Novakov, Christo
    Christova, Darinka
    Babeva, Tsvetanka
    POLYMERS, 2018, 10 (07)
  • [43] Synthesis and characterization of polymer brushes of poly(N,N-dimethylacrylamide) from polystyrene-latex by aqueous atom transfer radical polymerization
    Jayachandran, KN
    Takacs-Cox, A
    Brooks, DE
    MACROMOLECULES, 2002, 35 (11) : 4247 - 4257
  • [44] Eu3+- and Tb3+-Based Coordination Complexes of Poly(N-Isopropyl,N-methylacrylamide-stat-N,N-dimethylacrylamide) Copolymer: Synthesis, Characterization and Property
    Li, Jian
    Cui, Guihua
    Bi, Siyuan
    Cui, Xu
    Li, Yanhui
    Duan, Qian
    Kakuchi, Toyoji
    Chen, Yougen
    POLYMERS, 2022, 14 (09)
  • [45] Preparation and characterization of biocompatible and thermoresponsive micelles based on poly(N-isopropylacrylamide-co-N,N-dimethylacrylamide) grafted on polysuccinimide for drug delivery
    Yeh, Jih-Chao
    Hsu, Ya-Ting
    Su, Chao-Ming
    Wang, Ming-Chen
    Lee, Tsong-Hai
    Lou, Shyh-Liang
    JOURNAL OF BIOMATERIALS APPLICATIONS, 2014, 29 (03) : 442 - 453
  • [46] Preparation and Performance of Poly(vinylidene fluoride)-Based Crosslinked Gel Polymer Electrolytes
    Xiao Q.
    Chen Y.
    Li Q.
    Ren S.
    Gaofenzi Cailiao Kexue Yu Gongcheng/Polymeric Materials Science and Engineering, 2020, 36 (08): : 1 - 10
  • [47] AMPHIPHILIC NETWORKS .3. SYNTHESIS AND CHARACTERIZATION OF, AND DRUG RELEASE FROM POLY(N,N-DIMETHYLACRYLAMIDE)-L-POLYISOBUTYLENE
    IVAN, B
    KENNEDY, JP
    MACKEY, PW
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1990, 200 : 301 - POLY
  • [48] Effect of Electric Field Voltage on the Efficiency of Separation of Single-Stranded DNA Fragments by Capillary Gel Electrophoresis in Polymers Based on Linear Poly(N,N-Dimethylacrylamide)
    Bocharova, D. V.
    Alekseev, Ya. I.
    Kurochkin, V. E.
    JOURNAL OF ANALYTICAL CHEMISTRY, 2020, 75 (12) : 1633 - 1637
  • [49] Contact-Line Recession Leaving a Macroscopic Polymer Film in the Drying Droplets of Water-Poly(N,N-dimethylacrylamide) (PDMA) Solution
    Kajiya, Tadashi
    Monteux, Cecile
    Narita, Tetsuharu
    Lequeux, Francois
    Doi, Masao
    LANGMUIR, 2009, 25 (12) : 6934 - 6939
  • [50] Synthesis and characteristics of biodegradable and temperature responsive polymeric micelles based on poly(aspartic acid)-g-poly(N-isopropylacrylamide-co-N,N-dimethylacrylamide)
    Yeh, Jih-Chao
    Yang, Huei-Hung
    Hsu, Ya-Ting
    Su, Chao-Ming
    Lee, Tsong-Hai
    Lou, Shyh-Liang
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2013, 421 : 1 - 8
12345