Self-Assembly of TbPc2 Single-Molecule Magnets on Surface through Multiple Hydrogen Bonding

被引:15
|
作者
Pedrini, Alessandro [1 ,2 ]
Poggini, Lorenzo [3 ,4 ]
Tudisco, Cristina [5 ,6 ]
Torelli, Martina [1 ,2 ]
Giuffrida, Antonino E. [5 ,6 ]
Bertani, Federico [1 ,2 ]
Cimatti, Irene [3 ,4 ]
Otero, Edwige [7 ]
Ohresser, Philippe [7 ]
Sainctavit, Philippe [7 ,8 ]
Suman, Michele [9 ]
Condorelli, Guglielmo G. [5 ,6 ]
Mannini, Matteo [3 ,4 ]
Dalcanale, Enrico [1 ,2 ]
机构
[1] Dept Chem Life Sci & Environm Sustainabil, Parco Sci 17-A, I-43124 Parma, Italy
[2] INSTM RU Parma, Parco Sci 17-A, I-43124 Parma, Italy
[3] Univ Florence, Dept Chem Ugo Schiff, Via Lastruccia 3, I-50019 Sesto Fiorentino, Italy
[4] Univ Florence, INSTM RU Firenze, Via Lastruccia 3, I-50019 Sesto Fiorentino, Italy
[5] Univ Catania, Dept Chem Sci, Viale Andrea Doria 6, Catania, Italy
[6] Univ Catania, INSTM RU Catania, Viale Andrea Doria 6, Catania, Italy
[7] Orme Merisiers St Aubin, Synchrotron SOLEIL, BP 48, F-91192 Gif Sur Yvette, France
[8] UPMC, IRD, MNHN, IMPMC UMR7590,CNRS, 4 Pl Jussieu, F-75005 Paris, France
[9] Barilla GR Ili SpA, Adv Lab Res, Via Mantova 166, I-43122 Parma, Italy
关键词
multiple hydrogen bonding; UPy-NaPy self-assembly; SMM; terbium double deckers; PHTHALOCYANINE; SPIN; HYSTERESIS; SILICON; NANOPARTICLES; SPECTROSCOPY; MONOLAYERS; DRIVEN; XPS;
D O I
10.1002/smll.201702572
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The complexation between 2-ureido-4[1H]-pyrimidinone (UPy) and 2,7-diamido-1,8-naphthyridine (NaPy) is used to promote the mild chemisorption of a UPy-functionalized terbium(III) double decker system on a silicon surface. The adopted strategy allows the single-molecule magnet behavior of the system to be maintained unaltered on the surface.
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页数:7
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