An electroinitiated cation chain reaction: Intramolecular carbon-carbon bond formation between thioacetal and olefin groups

被引：49

作者：

Matsumoto, Kouichi ^{[1
]}

Fujie, Shunsuke ^{[1
]}

Ueoka, Koji ^{[1
]}

Suga, Seiji ^{[1
]}

Yoshida, Jun-ichi ^{[1
]}

机构：

[1] Kyoto Univ, Dept Synthet & Biol Chem, Grad Sch Engn, Nishikyo Ku, Kyoto 6158510, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 13期

关键词：

carbocations; electrochemistry; oxidation; sulfur; synthetic methods;

D O I：

10.1002/anie.200705748

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) The treatment of an olefinic thioacetal with a catalytic amount of ArS(ArSSAr)-+B(C6F5) 4-, or the electrolysis of a mixture of an olefinic thioacetal and ArSSAr, gives rise to effective intramolecular carbon-carbon bond formation (see scheme). This transformation opens up great potential for electroinitiated cation chain reactions in organic synthesis. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：2506 / 2508

页数：3

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