Synthesis of organosilanylene-oligothienylene alternate polymers and their applications to EL and FET materials

被引：29

作者：

Ohshita, J ^{[1
]}

Kim, DH

Kunugi, Y

Kunai, A

机构：

[1] Hiroshima Univ, Grad Sch Engn, Dept Appl Chem, Higashihiroshima 7398527, Japan

[2] Tokai Univ, Fac Engn, Dept Appl Chem, Hiratsuka, Kanagawa 2591292, Japan

来源：

ORGANOMETALLICS | 2005年 / 24卷 / 18期

关键词：

D O I：

10.1021/om050189t

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Monosilanylene-oligothienylene alternating polymers, [T-x-(SiBu2)](n) (MSxT, T = 2,5-thienylene or 3-butyl-2,5-thienylene, x = 8, 10, 12, and 14), were synthesized and their applications to electroluminescent (EL) devices and field effect transistors (FETs) were examined. The onset voltages for the luminance of EL devices with the structure of ITO/MSxT/Alq3/Mg:Ag were reduced on going from x = 10 to 14. However, the highest maximum luminance was achieved for x = 12 (900 cd/m(2)). The field effect carrier mobilities of the MSxT films were determined to be (3.4-6.9) x 10(-5) cm(2) V-1 s(-1), which increased with the length of the oligothiophene unit from x = 8 to 12, while increasing x from 12 to 14 barely affected the FET properties.

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页码：4494 / 4496

页数：3

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