Recent advances in crystalline hydrated borates with non-metal or transition-metal complex cations

被引：99

作者：

Beckett, Michael A. ^{[1
]}

机构：

[1] Bangor Univ, Sch Chem, Bangor LL57 2UW, Gwynedd, Wales

来源：

COORDINATION CHEMISTRY REVIEWS | 2016年 / 323卷

关键词：

Hydrated borates; Non-metal cations; Polyborate anions; Transition-metal complex cations; XRD; ORGANICALLY TEMPLATED PENTABORATE; HYDROGEN-BONDED PENTABORATE; ISOLATED POLYBORATE ANIONS; THERMAL-PROPERTIES; STRUCTURAL-CHARACTERIZATION; ZINC BORATE; BORIC-ACID; VIBRATIONAL SPECTROSCOPY; LUMINESCENT PROPERTY; COPPER PENTABORATE;

D O I：

10.1016/j.ccr.2015.12.012

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Structural aspects of crystalline hydrated polyborate salts containing polyborate anions partnered with either cationic transition-metal complexes or non-metal (organic) cations are documented. The structures are described in terms of Christ and Clark's and Burns' descriptors. The review, which concentrates on the period 2000-2015, also describes synthetic approaches (hydrothermal, solvothermal, flux methods) and physical and spectroscopic properties of the polyborate salts. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：2 / 14

页数：13

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