New cage isomers derived from hexaphospha-pentaprismane, P6C4tBu4

被引：16

作者：

Al-Ktaifani, MM ^{[1
]}

Hitchcock, PB ^{[1
]}

Nixon, JF ^{[1
]}

机构：

[1] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England

来源：

INORGANICA CHIMICA ACTA | 2003年 / 356卷

基金：

英国工程与自然科学研究理事会;

关键词：

UV irradiation; phosphorus; cage structure; crystal X-ray diffraction;

D O I：

10.1016/S0020-1693(03)00340-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

U-V irradiation of the hexaphospha-pentaprismane cage, P6C4'Bu-4, causes a structural rearrangement affording two new isomers, one involving a different closed cage structure and the other a more open cage structure containing one P=C double bond. The new closed cage isomer was also unexpectedly obtained as the sole product by protonation Of P6C4'Bu-4 with CF3SO3H. Both new P6C4'Bu-4 isomers were fully characterised by multinuclear NMR spectroscopy and single crystal X-ray diffraction studies. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：103 / 108

页数：6

共 50 条

[21] Two new modifications of [P(C6H5)(4)](2)[Cu2I4]
Pfitzner, A
Schmitz, D
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1997, 623 (10): : 1555 - 1560
[22] P-H FUNCTIONAL ZIRCONOCENE-PHOSPHIDO COMPLEXES - SYNTHESIS OF CP2ZR(PH(2,4,6-TBU3C6H2))(X) (CP=C5H5, X=CL, PH(2,4,6-TBU3C6H2)) AND MOLECULAR-STRUCTURE OF CP2ZR(PH(2,4,6-TBU3C6H2))2
HEYHAWKINS, E
KURZ, S
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 479 (1-2) : 125 - 133
[23] COLPOL, A NEW CYTOTOXIC C6-C4-C6 METABOLITE FROM THE ALGA COLPOMENIA-SINUOSA
GREEN, D
KASHMAN, Y
MIROZ, A
JOURNAL OF NATURAL PRODUCTS, 1993, 56 (07): : 1201 - 1202
[24] New copper complexes containing phosphaalkene ligands.: Molecular structure of [Cu{P(Mes*)C(NMe2)2}2]BF4 (Mes*=2,4,6-tBu3C6H2)
Weber, L
Krumberg, J
Stammler, HG
Neumann, B
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2006, 632 (05): : 879 - 884
[25] TRANSITION-METAL FUNCTIONALIZED PHOSPHAARSENES (ETA-5-C5H4H)-(CO)(PPH3)FE-AS=P-C6H2(TBU)3(2,4,6), (ETA-5-C5H4ME)-(CO)(PPH3)FE-AS=P-C6H2(TBU)3(2,4,6) AND 1,3,2,4-DIPHOSPHADIARSETANES [(ETA-5-C5ME5)(CO)2FE-AS-P-C6H2ME3(2,4,6)]2
WEBER, L
BUNGARDT, D
BOESE, R
BLASER, D
CHEMISCHE BERICHTE-RECUEIL, 1988, 121 (06): : 1033 - 1038
[26] Synthesis of Highly Refractive and Transparent Polyimides Derived from 4,4′-Thiobis[2",6"-dimethyl-4"-(p-phenylenesulfanyl)aniline]
You, Nam-Ho
Higashihara, Tomoya
Ando, Shinji
Ueda, Mitsuru
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2010, 48 (03) : 656 - 662
[27] Synthesis, crystal and molecular structures of the novel, structurally different, cage compounds P6C4Bu(t)4SiI2 and P6C4Bu(t)4GeI2, resulting from intra-molecular coupling of two 1,2,4-triphospholyl rings
Avent, AG
Cloke, FGN
Francis, MD
Hitchcock, PB
Nixon, JF
CHEMICAL COMMUNICATIONS, 2000, (10) : 879 - 880
[28] A NEW VANADIUM-III POTASSIUM PHOSPHATE WITH A CAGE STRUCTURE - K6V2P4O16
BENHAMADA, L
GRANDIN, A
BOREL, MM
LECLAIRE, A
RAVEAU, B
JOURNAL OF SOLID STATE CHEMISTRY, 1991, 91 (02) : 264 - 270
[29] SOME 4-ARYL-4,5,6,7-TETRAHYDROIMIDAZO[4,5-C]PYRIDINES DERIVED FROM HISTAMINE
STOCKER, FB
FORDICE, MW
LARSON, JK
THORSTEN.JH
JOURNAL OF ORGANIC CHEMISTRY, 1966, 31 (07): : 2380 - &
[30] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF [((ET(2)O)MG)(6)(NPH)(4)BR-4] - A MAGNESIUM-IMIDE CAGE SPECIES DERIVED FROM A DIMAGNESYLAMINE SOLUTION
HASCALL, T
OLMSTEAD, MM
POWER, PP
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1994, 33 (09): : 1000 - 1001

← 1 2 3 4 5 →