Coordination Structure of Bi atoms in Li2O-Bi2O3-B2O3 Glasses by X-ray Diffraction

被引：6

作者：

Fukumi, Kohei ^{[1
]}

Kitamura, Naoyuki ^{[1
]}

Kozuka, Hiromitsu ^{[2
]}

Kohara, Shinji ^{[3
]}

机构：

[1] Natl Inst Advance Ind Sci & Technol, Inorgan Funct Mat Res Inst, 1-8-31 Midorigaoka, Ikeda, Osaka 5638577, Japan

[2] Kansai Univ, Fac Chem Mat & Bioengn, Dept Chem & Mat Engn, 3-3-35 Yamate Cho, Suita, Osaka 5648680, Japan

[3] Natl Inst Mat Sci, Adv Key Technol Div, 1-1-1 Kouto, Sayo, Hyogo 6795148, Japan

来源：

JOURNAL OF THE CERAMIC SOCIETY OF JAPAN | 2018年 / 126卷 / 12期

关键词：

Glass structure; Li2O-Bi2O3-B2O3; Bi atoms; X-ray diffraction; CRYSTAL-STRUCTURE; OPTICAL-PROPERTIES; BISMUTH BORATE; PHOSPHATE; BASICITY; NEUTRON; PATTERN;

D O I：

10.2109/jcersj2.18112

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

The coordination structure around Bi atoms has been studied in Li2O-Bi2O3-B2O3 glasses by X-ray diffraction method. It was found that Bi atoms were coordinated by five or six oxygen atoms. The number of Bi atoms around a Bi atom through Bi-O-Bi bonds increased with an increase in Bi/O ratio. It was inferred that BiOx polyhedra were clumped in the glasses, although BiOx polyhedra were more clumped in Li2O-Bi2O3-B2O3 glasses than in Bi2O3-B2O3 glasses. (C) 2018 The Ceramic Society of Japan. All rights reserved.

引用

页码：992 / 996

页数：5

共 32 条

[1] Crystal growth and crystal structure of the metastable bismuth orthoborate BiBO3 [J].

Becker, P ;

Fröhlich, R .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2004, 59 (03) :256-258

[2]

Benmore, 2012, ISRN MAT SCI, V2012

[3] BOND-VALENCE PARAMETERS OBTAINED FROM A SYSTEMATIC ANALYSIS OF THE INORGANIC CRYSTAL-STRUCTURE DATABASE [J].

BROWN, ID ;

ALTERMATT, D .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1985, 41 (AUG) :244-247

[4] Electronic polarizability, optical basicity and non-linear optical properties of oxide glasses [J].

Dimitrov, V ;

Komatsu, T .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1999, 249 (2-3) :160-179

[5] INTERPRETATION OF GLASS CHEMISTRY IN TERMS OF OPTICAL BASICITY CONCEPT [J].

DUFFY, JA ;

INGRAM, MD .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1976, 21 (03) :373-410

[6] THE CRYSTAL-STRUCTURE OF BISMUTH BORATE, BIB3O6 [J].

FROHLICH, R ;

BOHATY, L ;

LIEBERTZ, J .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1984, 40 (MAR) :343-344

[7]

Gereben O, 2007, J OPTOELECTRON ADV M, V9, P3021

[8] LIBIO2 - A MODEL FOR BI-3+ COORDINATION IN HIGH-TEMPERATURE SUPERCONDUCTORS [J].

GREAVES, C ;

KATIB, SMA .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (14) :902-903

[9] CRYSTAL-STRUCTURE OF LI3BIO3 [J].

HOPPE, R ;

HUBENTHAL, R .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1989, 576 (09) :169-178

[10] CRYSTAL STRUCTURE OF BSIMUTH(2-1)BORATE, 2BI2O3.B2O3 [J].

HYMAN, A ;

PERLOFF, A .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL CRYSTALLOGRAPHY AND CRYSTAL CHEMISTRY, 1972, B 28 (JUL15) :2007-&

← 1 2 3 4 →