C60 adsorption onto the one-atomic-layer In films on Si(111) surface

被引:11
作者
Gruznev, D. V. [1 ]
Matetskiy, A. V. [1 ]
Gvozd, I. V. [1 ]
Zotov, A. V. [1 ,2 ,3 ]
Saranin, A. A. [1 ,2 ]
机构
[1] Inst Automat & Control Proc, Vladivostok 690041, Russia
[2] Far Eastern State Univ, Fac Phys & Engn, Vladivostok 690000, Russia
[3] Vladivostok State Univ Econ & Serv, Dept Elect, Vladivostok 690600, Russia
基金
俄罗斯基础研究基金会;
关键词
Atom-solid interactions; Silicon; Indium; Fullerene; Surface structure; Morphology; Roughness; Topography; Scanning tunneling microscopy (STM); ROOT 3-IN SURFACE; STM; TEMPERATURE; SUBSTRATE; GROWTH;
D O I
10.1016/j.susc.2011.07.008
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We have studied C-60 adsorption onto the In-induced Si(111) reconstructions, Si(111)2x2-In. Si(111)-hex-root 7 x root 3-In, and Si(111)-rec-root 7 x root 3-In, which all represent essentially one-atomic-layer In films residing atop a bulk-like Si(111) substrate. The reconstructions have various In densities, incorporating 0.75, 1.0, and 1.2 ML of In, respectively. We have found that C-60 adsorption onto these reconstruction is accompanied by the mass transport within In atomic layer, which is manifested by developing the domains of a more dense In/Si(111) reconstruction on the surface in between C-60. This observation provides a direct evidence for the displacement of In atoms from beneath C-60 to the surrounding surface area. The plausible driven force of the C-60-induced In displacement is a tendency of C-60 to change relatively modest bonding with In layer to a more stronger bond with Si(111) substrate. (C) 2011 Elsevier B.V. All rights reserved.
引用
收藏
页码:1951 / 1955
页数:5
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