Preparation and Oxygen Reduction Properties of Cu-N Co-doped Carbon-Based Catalysts

被引:1
作者
Li Si-Jia [1 ]
Zhu Jie [1 ]
Zheng Ji-Ming [1 ]
Geng Ji-Ye [1 ]
Li Yi-Bing [1 ]
机构
[1] Guilin Univ Technol, Coll Mat Sci & Engn, Guilin 541000, Guangxi, Peoples R China
关键词
oxygen reduction recation; transition metal-nitrogen co-doped; copper particles; FE/FE3C NANOPARTICLES; ELECTROCATALYSTS; GRAPHENE; PERFORMANCE;
D O I
10.11862/CJIC.2020.079
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
In order to solve the problems of high cost and poor stability of fuel cell cathode catalysts, Cu, N co-doped carbon based catalyst (Cu-N-KB) was prepared by simple heat treatment using alpha-nitroso-beta-naphthol copper, melamine and conductive carbon black. The characterization results show that Cu and N are uniformly distributed in the carbon support and the copper exists in the form of crystalline copper particles and amorphous Cu-N-x, The high specific surface area and mesoporous structure of the catalyst ensure a large number of active sites and fast mass transfer efficiency. The catalyst exhibits excellent oxygen reduction catalysis, methanol resistance and stability in an alkaline medium compared to commercial Pt/C catalysts.
引用
收藏
页码:627 / 635
页数:9
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