Living Ziegler-Natta polymerizations: True or false?

被引:23
作者
Busico, V [1 ]
Talarico, G [1 ]
Cipullo, R [1 ]
机构
[1] Univ Naples Federico II, Dipartimento Chim, I-80126 Naples, Italy
关键词
controlled; living; polypropylene; Ziegler-Natta polymerization;
D O I
10.1002/masy.200550801
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Based on the recent literature, the synthesis of novel polyolefin architectures via Ziegler-Natta chemistry under living conditions appears to be a promising and fast-growing area. In this paper, the appropriateness of the term "living" as applied to the said context is discussed in mechanistic terms, and the potential and the limitations of the field are outlined with the aid of two paradigmatic case histories (i.e., propene polymerization in the presence of bis(phenoxy-imine)Ti and bis(phenoxy-amine)Zr catalysts).
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页码:1 / 16
页数:16
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