The low-temperature water-gas shift reaction catalyzed by sodium-carbonate-activated ruthenium mono(bipyridine)/SiO2 complexes

被引:18
|
作者
Luukkanen, S [1 ]
Haukka, M [1 ]
Kallinen, M [1 ]
Pakkanen, TA [1 ]
机构
[1] Univ Joensuu, Dept Chem, FIN-80101 Joensuu, Finland
关键词
ruthenium; bipyridine; catalyst; WGSR;
D O I
10.1023/A:1018881100163
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The effect of a new catalyst activation method on the catalytic activities of several chlorine-containing ruthenium mono(bipyridine) carbonyl complexes in the water-gas shift reaction (WGSR) was studied. The chemical activation of the silica-supported complexes by a sodium carbonate/methanol solution under CO atmosphere produced highly active low-temperature water-gas shift reaction catalysts.
引用
收藏
页码:123 / 125
页数:3
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